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MEPOXE MA Methyl Ethyl Ketone Peroxide type MA Mepoxe is the catalyst specially made for the polymerization of unsaturated polyester resin. It is solution mixture of methyl ethyl ketone peroxide in phthalate plastilizer.
Specifications and Properties : Appearance :
Clear, Colorless liquid
Phthalate plastilizer :
50 ± 5%
Active Oxygen :
9.5 ± 0.5%
Specific Gravity :
1.13 (at 20°C)
Flash Point (Closed cup) :
50°C minimum
Solubility insoluble :
Water, Glycerine, Petroleum
Soluble :
Esters, Alcohols, Ketones, Ethers
Packaging : Supply Container ( type )
Polyethylene Jerrycan, carton box
Supply Container ( Contents NW )
4 jerrycan x 5kg = 20kg/carton box 1 jerrycan x 20kg = 20kg/carton box
PT. KAWAGUCHI KIMIA INDONESIA Office
Factory
: Jl. Hayam Wuruk No. 44 Lt. II/2 B, Jakarta (11160) – INDONESIA Phone : (6221) 6498693, 6263179 Fax : (6221) 6260973 : Jl. Raya Serang KM. 12,5 Cikupa – Tangerang 15170
MSDS : Mepoxe MA (P. 1/4)
MATERIAL SAFETY DATA SHEET
Date of issue : 11 May 2009
1. Identification of the product and the company Product Name : MEPOXE MA Company Name : PT. Kawaguchi Kimia Indonesia Office Address : Jl. Hayam Wuruk no. 44 Lt. II / 2B, Jakarta 11160, Indonesia. Tel. No : (62 – 21) 6498693, 6263477 Fax No : (62 – 21) 6260973 Email : [email protected] Intended Use : Hardening agent for the polymerization of unsaturated polyester resins. 2. Hazard and Harm Identification Classification : Organic peroxide type D. Inflammable liquid' Hazardous : Heating generates fire and explosion. Harmful : Harmful if swallowed. Skin, mucous membrane and eyes air irritated. 3. Composition and Ingredients Information Classification : Mixture Chemical Name : Methyl Ethyl Ketone Peroxide Chemical Name
Chemical Formula
CAS No.
Content (wt%)
(C4H8O2)n
1338234
30 – 40
Dimethyl Phthalate
C10H10O4
131113
45 – 55
Methyl Ethyl Ketone
C4H8O
78933
Max 5
Hydrogen Peroxide
H2O2
7722841
Max 5
Methyl Ethyl Ketone Peroxide
4. First Aid Measures General Inhalation Skin Eye Swallow
: Call a physician immediately. : Remove to fresh air space. If difficulty in breathing, keep warm and get medical treatment immediately. : Immediately wash skin with water and soap. If be unusual, get medical check. : Immediately wash eyes with water for at least 15 minutes. After that get medical treatment. In case eyes to do contact lenses, if don't stick eyes, remove lenses then wash eyes. : In case be consciousness, immediately rinses out mouth then give a cup of water. After that get medical treatment. And don't induce vomiting. In case be unconsciousness, immediately get medical treatment. At the time if vomiting occurs, the patient should lie on their left side while vomiting to reduce the risk of aspiration.
5. Fire Fighting Measures Extinguishing Media : Water spray, Dry chemical powder, CO2, Alcohol resistant foam. Hazardous decomposition, combustion products. : Carbon monoxide and poisonous gas by decomposition reaction. Method of extinguish a fire : Extinguish a small fire with powder or carbon dioxide ten apply water to cool. Extinguish a big fire with water bar or spray or foam or reinforced liquid then apply water to cool. Escape the fire with many water.
MSDS : Mepoxe MA (P. 2/4)
Protect for the fire fighter : Must wear proper protective equipment. Extinguish a fire from the windward for avoids inhalation poisonous gas. Keep the safety distance because there is an explosion hazard. 6. Accidental Release Measures Caution for Human : Must wear proper protective equipment and work from the windward. Stretch rope at leaking area and keep out except person concerned. Ventilate at leaking area, if necessary. Caution for environment : Don't allow direct to enter drain or water courses. Method for cleaning up : In case small, wipe off with cloth then burns in safety space immediately. In case large, stop an outflow with earth and sand then collect. Adsorbs remainder with sawdust, diatomite or dry sand then disposes of proper. Soaks water if keeps for the time. Prevention for secondaly disaster : Remove the sources of ignition in neigborhood immediately. Use the safety tools as don't generate sparks. 7. Handling and Storage Handling : Handle well in ventilated area. Wear proper protective equipment for guard eyes and skin. Avoid strong rubbing and shock. Eliminate all sources of ignition, and don't generate flames or sparks. Keep away from reducing agents, amines, acids, alkalies and heavy metal compounds. Use materials of equipment stainless steel, glass lining, polyethylene. Don't use irons, copper compounds, leads, and rubbers. Take measures for static electricity as ground. Use explosion protected equipment. Wash empty container with water at once, after then put the cap and avoid the direct sunlight. Storage : Store in accordance with local and national regulations. Keep in the cool dark place of less than 30oC. Don't use fire. Keep away from food, drink and other chemicals, especially amines, acids, alkalies, heavy metal compounds and reduction agents. Take measures for the fall and the fall prevention. Must not put the horizontal and the reverse. Container : Use materials stainless steel, glass lining, polyethylene for avoids decomposition. 8. Exposure Controls and Human Protection Equipment : Set the local exhaust ventilation when gas and mist are generated. Set the washing tool for eyes and body. Use explosion protected equipments. Take measures the static electricity. Allowable Concentration Shot Term Exposure Limit (STEL) : Methyl Ethyl Ketone Peroxide 0.2 ppm (Ceiling) : Methyl Ethyl Ketone 300 ppm Time Weighted Average (TWA) : Methyl Ethyl Ketone 200 ppm : Dimethyl Phthalate 5 mg / m3 : Hydrogen Peroxide 1 ppm
MSDS : Mepoxe MA (P. 3/4)
Human Protection Respiration Organs Hand Eyes Skin and body
: : : :
Wear the organic gas proof mask. Wear the unpermeation gloves. Wear the glasses or goggles. Wear the shirt with long sleeves and safety shoes.
9. Physical and Chemical Properties Appearance : Clear liquid Color : Colorless Odor : Characteristic odor Melting point : No data Coagulating point : No data Boiling point : Impossible to measure because generates decomposition Flash point : 50oC (Closed cup, Seta direct vent type) Ignition point : 197oC (ASTM E 659) Specific gravity : 1.130 at 20oC Insoluble : Water, Glycerine, Petroleum Soluble : Ketones, Ethers, Alcohols, Esters 10. Stability and Reactivity Stability : Instability to heat. SADT = 65oC Avoid the direct sunlight and strong rubbing and shock. Keep away fire and heat. Reactivity : Self reactiveness. Promoted decomposition with amines, acid, alkalies, heavy metal compounds and reduction agents. Avoid using materials of iron, copper compound and rubber. 11. Toxicological Information Acute toxicity : The following data are the diluted to 60% solution with dimethyl phthalate. Oral : Rat LD50 1051mg/Kg 1) Human TDLo 480mg/Kg 2) Mouse LD50 470mg/Kg 3) Inhalation : Mouse LC50 170ppm/4hours exposure time 4) Abdominal cavity : Rat LD50 65mg/Kg 4) Mouse LD50 200mg/Kg 5) Localized Influence Skin : Rabbit Corrosive 1) Rabbit the highest density doesn't stimulates 1.5% 4) Eyes : Strong corrosive and stimulative. 6) Rabbit the highest density doesn't stimulates 0.6% 4) Carcinogenic : Not mention of NTP, IARC, OSHA. 7) Mutation field of the generative cell : Gloomy 8) 12. Ecological Information Toxicity to ecology : No data Remain / Decomposition : No data Accumulation : No data
MSDS : Mepoxe MA (P. 4/4)
13. Disposal Consideration General : It disposes properly according to the law in each country and the region. Incinerate : Use proper incinerator. When the incineration is done,it incinerates little by little mixing it with an inert high boiling point solvent. Or, the diatom soil and the vermiculite, etc. are made to absorb it and it burns. If there is no proper incinerator, the consignment disposal is done to the industrial waste trader who obtains permission. Contaminated packing: Removed contents completely after then incinerated. 14. Transport Information General Classification UN Number Sea transport Air transport Safety measures
: : : : : :
It disposes properly according to the law in each country and the region. 5.2 Organic Peroxide 3105 Organic Peroxide type D liquid Follow method of transport, be provided in IMDG. Follow method of transport, be provided in IATA. Take measures for the fall and the fall prevention, for prevent leakage. The top of container turned upward, must not put the horizontal and the reverse. When transport, keep out inflammable. Avoid direct sunlight and heat.
15. Application of Regulations Fire Defense Law : Classification 5.2 self reactiveness Industrial Safety and Health Law : Dangerous substances Safety of Vessel law : Oxidized material. Organic peroxide Aviation law : Organic Peroxide. (It is forbidden to air transportation) 16. Other Information References : 1. Data of Company 2. National Clearinghouse for Poison Control Centers, Bulletin., Jan/F 3. J.Am.Med.Assoc., 165.201.57 4. Floyd, Ep and H.E.Stokinger : Amer.Ind.Hyg.Assoc.J., 19.205.58 5. Hygiene and Sanitation 29.103 (January 1964) 6. Report of International Research and Development Corporation, Mattawan, Michigan IRDC 328004 7. The Nippon Chemical Industrial Co., Ltd. Safe material and United States OHSA.. Dangerous, harmful, wellknown, standard rule and clearinghouse edit (issue on July 2, 2001).. list of a dangerous harmful chemical. (the fifth edition) 8. Report of Central Institute voor Voedingsonderzoek TNO (CIVO), Zeist, Holland