George Wypych (Auth.) - Antistatics Databook (2014, ChemTec) PDF [PDF]

Zitiervorschau

Databook of Antistatics George Wypych

Toronto 2014



Published by ChemTec Publishing 38 Earswick Drive, Toronto, Ontario M1E 1C6, Canada



© ChemTec Publishing, 2014 ISBN 978-1-895198-77-5



Cover design: Anita Wypych

All rights reserved. No part of this publication may be reproduced, stored or transmitted in any form or by any means without written permission of copyright owner. No responsibility is assumed by the Author and the Publisher for any injury or/and damage to persons or properties as a matter of products liability, negligence, use, or operation of any methods, product ideas, or instructions published or suggested in this book.

Library and Archives of Canada Cataloguing in Publication Wypych, George, author Databook of antistatics / George Wypych Includes index. Electronic monograph. Issued also in print format ISBN 978-1895198-77-5 1. Polymers--Antistatic additivies. 2. Polymers--Antistatic additives--Healths aspects. 3. Polymers--Antistatic additives-Environmental aspects. I. Title

TP1142.W4683 2013

668.9

C2013-905638-6

1 Introduction 1.1 Electrostatic charge generation A typical surface of solid material has 2x1019 atoms per m2. Considering that one electron carries a charge of 1.6x10-19 coulomb and the breakdown field strength of air is 3x106 V per m, the maximum charge density on the surface of a solid is 2.64x10-5 coulomb per cm2, and this is equivalent to a loss or a gain of 1.65x1017 electrons per m2. This means that one electron has to be removed from 121,000 atoms on a surface to create the maximum surface charge before discharge occurs.1 Charge formation may occur either by a separation of contacting bodies or by implanting electrons on a body surface by a non-contacting method. In both cases, the preservation of charges in position on a surface depends on the property of a body, namely its conductivity. If a body is a conductive material the charges move and they are eventually lost. If a body has the insulating properties, then charges are becoming “static”, which means that they stay in the place at which they were deposited (though there is always some leakage of charges due to conductivity). It is usually assumed that materials able to hold charges have resistance in excess of 106 ohm. It is characteristic of static electricity that large potentials are generated (0.1 to 100 kV) but only very small currents (0.01 to 100 A) are produced.2 Three typical cases of charge formation by separation of bodies can be distinguished:3 • two bodies in contact are separated by sliding against each other (e.g., sliding out of shipping tube, separation of web from a roll, unwinding, etc.) • repetitive separation (e.g., walking on an insulating surface) • quasi-continuous contact and separation (e.g., pneumatic transport of solid particulates, flow of liquids trough pipes, etc.). From the above information, it is quite obvious that the charges formed on two materials have the same magnitudes but different signs, considering that one has lost and the other accepted the same electrons. The charge generation is facilitated by a frictional contact and it is frequently called tribocharging. This effect was recognized in 600 BC by Thales of Miletus, who observed that amber attracted particles of dust when it was rubbed with some materials. Materials differ in the energy required to remove an electron from the sphere of influence of its nucleus. This can be quantified based on a work function, which is the minimum energy that must be given to an electron to liberate it from the surface of a particular material. The work function of different materials is the basis of a material’s position in the triboelectric series (Table 1.1). Table 1.1. Triboelectric Series Work function, eV (+) positive end Human hands Asbestos Rabbit fur Glass Mica Human hair Polyethyleneoxide Polyamide 66 Polyvinylacetate Wool Antistatics Databook / Copyrights 2014; ChemTec Publishing

3.95 4.3-4.5 4.38 1

Fur Lead Silk Aluminum Paper Cotton (approx. in the middle of the scale) Steel Wood Amber Sealing wax Hard rubber Polyaniline Brass, silver Iron Sulfur Acrylics Polyester Polycarbonate Polyethylene Polystyrene Polysulfone Polyepichlorohydrine Nickel, copper Polyurethane Polyethylene Polypropylene Polyvinylchloride Platinum (-) negative end Polytetrafluoroethylene

4.25 4.28-4.53

4.5-4.7 4.5-4.7 4.60 4.7-5.5 4.8-5.57 4.90 4.90-5.48 4.95 4.95 5.0-5.1

5.13 5.65 5.75-5.8

Materials at the top of triboelectric series charge negatively when contacted with materials listed below them, which charge positively. There are large discrepancies between different origins of data (some are reflected in the table by a range of values recorded in different research). If polyamide (high in the triboelectric series) contacts polyvinylchloride, polyamide loses more electrons to polyvinylchloride than polyvinylchloride to polyamide. As the end result, polyvinylchloride gains electrons and its surface accumulates a negative charge, but polyamide has a positive charge. Because both polymers have very high resistance, the charge remains (it will leak or decay slowly) for a considerable time. It is also expected that the lower the difference between the work function of materials, the lower the charge generated. The trend is generally correct but the separation of the same materials also generates a charge which is not consistent with this rule. It is likely that these departures in behavior are caused by a presence of impurities and by asymmetrical rubbing. Non-uniform rubbing creates a temperature gradient which contributes to differences in electron imbalance in different locations of a surface. It should be noted that it is difficult to predict which side of material will have more electrons, but it is most likely that each side will have positively and negatively charged areas.1

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1.2 Electromagnetic interference Electromagnetic radiation is a result of changes in electrical current or voltage levels. This radiation occurs at discrete frequencies. Electromagnetic interference, EMI, occurs when • a source of electromagnetic energy exists • a receptor is susceptible to a particular amplitude and frequency of transmitted source energy. Electromagnetic energy is generated in the form of spherical wave fronts, which travel in all directions from the source. At any given point, the wave consists of an electric field and a magnetic field, which are perpendicular to each other and to the direction of propagation. EMI can be conducted or radiated. If the source is connected to the receptor by power or signal cables, the interference is propagated (or conducted) from one unit to the other along the cables. We can control conducted interference by EMI filters. Radiated EMI occurs when a component emits energy, which is transferred to a receptor through the atmosphere. Radiated interference is difficult to shield because it can affect any signal path within the electronic equipment. Many sources of EMI can be distinguished:3 • natural (lightning, static discharge, cosmic radiation, and corona discharge) • electrical and electronic equipment (TV, radio, radar, navigations aids, and cellular phones) • industrial (arc welding, ultrasonic cleaning, automated controls, computers, power tools, and machines) • commercial (cash registers, internal communication systems, and computers) • consumer goods (car ignition systems, power tools, children toys, home safety protection systems, remote controls, pagers, etc.). All these sources of electromagnetic interference influence performance of the very appliances which were listed above as the sources of interference. Radiated EMI may be eliminated or reduced by the use of shielded enclosures and shielding materials. The second method for establishing electromagnetic compatibility, EMC, is to improve or reduce its susceptibility to interference from external EMI sources. Susceptibility to external EMI may be reduced or even eliminated by designing circuits and choosing components which are inherently less sensitive to interference. In current practice both methods are used. EMI can be controlled by: • preventing emissions from appliances • acting in the transmission path (or shielding). Design of circuits which do not emit EMI is ideal as a solution but difficult to achieve and expensive. Shielding against EMI is a more practical and desirable approach than changing the board layout or choosing components because they are non-invasive to the circuitry. Shielding does not influence the system speed while containing its own emissions and providing good prevention against EMI from outside sources. Also, it requires no alteration of the board layout. Depending on the design, shielding may not be affected even by future system upgrades. Wave impedance is an important concept in understanding EMI shielding. It is a ratio of electric field, measured in V/m, to magnetic field, measured in A/m. This means that low voltage and high current give low wave impedance. Conversely, high voltage and low current give high wave impedance. An electromagnetic wave can be in near-field or far-field, depending on its distance from the source. The transition region of one to another is at a distance of /2 from the source, where  is a wavelength of EMI radiation. When the operating frequency of an electronic device increases, far-field shielding becomes predominant. Antistatics Databook / Copyrights 2014; ChemTec Publishing

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The wave impedance in the near-field region is largely determined by the source. The wave impedance in the far-field region is largely determined by the propagating medium. This affects shield design. For example, for emission control, the shield must be designed for the near-field region. A high current source requires a magnetically permeable shield and a high voltage source requires an electrically conductive shield. The greater the mismatch between the wave impedance and the shield’s impedance, the greater is the reflection of the wave away from the direction of propagation. The effectiveness of an EMI shield is determined by energy: • reflected by a shield • absorbed within a shield • re-reflected from the back surface of a shield. The re-reflected energy can add or subtract from shielding, depending on the phase relationship with the incident radiation. The effectiveness of a shield is the sum of reflected and absorbed energy plus a correction factor to account for re-reflections. The main methods of EMI shielding include: conductive coatings, laminates/tapes, conductive plastics/elastomers. Major influences in the EMI market include:4 • increasing frequencies due to higher chip speeds • search for cheaper alternatives • improved potential of the EMI business because of development of wireless technologies • environmental pressures on metal disposal • new developments in shielding technology. Not mentioned on this list are governmental regulations which require manufacturers to provide results of tests which confirm their products non-interfering behavior. National and international standards specify EMI limits. Some also specify minimum levels of immunity. Emission control and suppression of internally generated signals prevents radiated or conducted emissions. The main bodies that control legislation and standards are the FCC in the USA, the CSA in Canada, VCCI in Japan, AUSTEL in Australia, and the legislation by EU member countries (EN 50081). Electronic products must be tested, verified, and certified according to standards set by these organizations before products are sold. Immunity controls are usually established by companies own standards. There are no immunity requirements in the USA but EU regulations include immunity (EN 50082). Cross-talk control affects mostly mobile or portable equipment. Since this affects product performance, it is controlled at the manufacturer design level. It should be noted that public is aware of dangers of electromagnetic radiation (e.g., cellular phones) and there is strong pressure to eliminate this problem. References 1. Blacker, R. S.; Birley, A. W., Polym. Testing, 10, 4, 241-62, 1991. 2. Britton, L. G., Avoiding Static Ignition Hazards in Chemical Operations, 2nd Ed., Center for Chemical Process Safety/AIChE, 1999. 3. Drake, N., Polymeric Materials for Electrostatic Applications, Rapra Technology, Shawbury 1996. 4. Schlechter, M., EMI: Materials and Technologies, Research Report # GB-066Y, BCC, July 2003.

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2 Information on data fields Glossary of terms and methods of testing used in the databook is given in alphabetical order. The information on data in a particular field includes glossary of term, unit of measurement, typical methods used to measure quantities available in the database. Acid number Twenty-five grams of a additive is placed in 125 ml Erlenmeyer flask and 50 ml alcohol is added to dissolve the sample. If the sample is not completely soluble, 50 ml of equal amounts of alcohol and acetone are used. This sample is titrated with 0.01N NaOH or KOH in the presence of bromothymol blue used as an indicator. ISO standard uses a method of titration similar to just described ASTM standard but phenolphthalein is used as an indicator and 0.1 N NaOH is used as a titrating agent. The results are expressed in mg KOH per 1 g of sample. Acidity The results of titration (see Acid number) are expressed in weight percents as acetic acid. Acronym Abbreviations of additive names can be found in the standard terminology (ASTM D160013 Standard Terminology for Abbreviated Terms Relating to Plastics). ISO standard has a separate section for symbols used for additives (ISO 1043-3:1996 Plastics -- Symbols and abbreviated terms -- Part 3: Additives). In addition to the abbreviations for individual additives, Annex A contains a list of symbols for additive components (alcohol part, acid part, and other elements of composition). Abbreviations of additives used in rubber are given in a separate standard (ISO 6472:2010 Rubber compounding ingredients -- Symbols and abbreviated terms). Additive application method Method of additive application (e.g., spraying, dipping, etc.). ADR/RID class A number corresponding to one of the eight classes of cargo defined in the European Agreement concerning the International Carriage of Dangerous Goods by Road (ADR) or the International Regulations concerning the Transport of Dangerous goods by Rail (RID). Alkyl distribution The percentages are given of alkyl parts if additive is made from a mixture of fatty acids or fatty alcohols. Amine number Twenty-five grams of a additive is placed in 125 ml Erlenmeyer flask and 50 ml alcohol is added to dissolve the sample. If the sample is not completely soluble, 50 ml of equal amounts of alcohol and acetone are used. This sample is titrated with 0.01N HCl in the presence of bromothymol blue used as an indicator. The results are expressed in mg HCl per 1 g of sample. Amine, primary The percentage of primary amine in the mixture of all amines. Antistatics Databook / Copyrights 2014; ChemTec Publishing

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Animal testing, acute toxicity Acute toxicity describes the adverse effects resulting from a single exposure to a substance. Typical methods of measurement include LD50 which is the amount of a solid or liquid material that is required to kill 50% of test animals in one dose. Aquatic toxicity The adverse effects to marine life (aquatic organisms) that result from exposure to a toxic substance. Aquatic toxicity can be expressed as the lethal concentration of a chemical substance in miligrams per liter that caused death to 50% population of aquatic species (LC50) during a time of experiment (usually 24, 48 or 96 hours). Ash Fraction of ash in % usually determined by ashing sample to constant weight at 900oC. Autoignition temperature The lowest temperature at which a material will ignite and sustain combustion in the absence of a spark or flame. The properties of liquid can be tested by standardized methods (ASTM E659-78 (2005) Standard Test Method for Autoignition Temperature of Liquid Chemicals). The ignition temperature is the temperature in degrees Centigrade at which the substance shows spontaneous combustion when touching hot bodies. Biodegradation probability The probability that an organic substance will biodegrade under aerobic conditions. This field includes the general statements regarding biodegradation probability of additives. Experimental data are included in the following fields: Biological Oxygen Demand, Chemical Oxygen Demand, and Theoretical Oxygen Demand. Biological Oxygen Demand The biological oxygen demand, BOD, is the mass concentration of dissolved oxygen consumed under specific conditions in a given time (e.g., BOD-5 stands for 5 days test) by the aerobic biological oxidation of a chemical or organic matter in water. BOD is an empirical test, which evaluates the ultimate aerobic biodegradability of organic compounds in water. The following ISO standards can be applied: ISO 10708:1997 Water quality -- Evaluation in an aqueous medium of the ultimate aerobic biodegradability of organic compounds -- Determination of biochemical oxygen demand in a two-phase closed bottle test and ISO 58151:2003 Water quality -- Determination of biochemical oxygen demand after n days, BODn. Boiling point The boiling point is the temperature in degrees Centigrade at which the substance undergoes transition from the liquid into the gaseous phase under normal pressure. Bulk density The bulk density is defined as the mass of additive divided by its total volume. The bulk density is expressed in kg/m3. Bluegill sunfish In order to assess bioaccumulation of substance, a test organism such as Bluegill sunfish, Daphnia magna, Fathead minnow, Rainbow trout, or other is selected. The test substance is administered as a suspension directly into the water. A test organism is observed by a Antistatics Databook / Copyrights 2014; ChemTec Publishing

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specified number of hours. If deleterious effects, due either to toxicity or pathogenicity are observed, sequentially lower doses should be tested. The experiment should establish LC50 value for a particular substance and a test organism (LC50 is a dose required to kill 50 percent of the test organisms). Carcinogenicity A carcinogenic material is one that is known to cause cancer. The process of forming cancer cells from normal cells or carcinomas is called carcinogenesis. A summary of findings included in this field is based on general principles of material assessment, which includes: a  There is limited evidence of carcinogenicity from studies in humans. A cause and effect interpretation is credible, but that alternative explanations such as chance, bias, other variables etc. cannot be ruled out. Again, science can never prove a hypothesis, only disprove one. Scientific “facts” are established only when a preponderance of the evidence supports a hypothesis and there is 1) no evidence to disprove it and 2) no equally viable alternative hypotheses. b  There is sufficient evidence of carcinogenicity from studies in experimental animals, which indicates there is an increased incidence of malignant and/or a combination of malignant and benign tumors (1) in multiple species or at multiple tissue sites, or (2) by multiple routes of exposure, or (3) to an unusual degree with regard to incidence, site, or type of tumor, or age at onset. c  There is less than sufficient evidence of carcinogenicity in humans or laboratory animals; however, the substance is structurally related to other materials that are either human carcinogens or reasonably anticipated to be human carcinogens. d  There is convincing relevant information that the material acts through mechanisms that are likely to cause cancer in humans. Carrier resin A resin in which additive(s) are pre-dispersed CAS number A number assigned by the Chemical Abstracts Service that uniquely identifies a chemical substance. Chemical category Non-systematic classification of additives based on their main or active component. Chronic effect A chronic health effect is an adverse health effect resulting from long-term exposure to a substance. The effects could be a skin rash, bronchitis, cancer or any other medical condition. The term is also applied to a persistent (months, years or permanent) adverse health effect resulting from a short-term (acute) exposure. Coefficient of friction The ratio of the weight of an object being moved along a surface and the force that maintains contact between the object and the surface. Coefficient of thermal expansion The coefficient of thermal expansion is a fractional increase in volume per unit rise in temperature.

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Concentration of active ingredient(s) Concentration of pure additives used for a particular purpose. Color This field gives a description of color that is typical of commercial product or pure specimen. Color, Gardner scale Gardner color scale is made of arbitrary glass standards numbered from 1 to 18. Measurements are made according to standardized method (ASTM D1544-04 (2010) Standard Test Method for Color of Transparent Liquids (Gardner Color Scale)). Color, platinum-cobalt scale Platinum-cobalt scale was originally developed by Hazen and it is sometimes referred to as Hazen color or APHA color because it was developed by the American Public Health Association for determining the color of water. Both names are incorrect because they do not reflect procedures used in the current method (ASTM D1209-05 (2011) Standard Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)). Platinum cobalt reference standards are solutions of potassium chloroplatinate and cobalt chloride, which have different concentrations. They can be prepared from these chemical reagents or purchased as ready made standards. Measurement is made in a visible spectrophotometer by comparison of readings for sample and standards and selection of the closest standard. If the color lies midway between standards, a darker standard is reported. ISO standard provides a procedure which is based on the original Hazen platinum-cobalt scale (ISO 2211:1973 Liquid chemical products -Measurement of colour in Hazen units (platinum-cobalt scale)). The results of testing based on color comparison of the test tubes and the additive are given in Hazen units. Platinumcobalt scale is used for estimation of color of clear liquids (ISO 6271-2:2004 Clear liquids -- Estimation of colour by the platinum-cobalt scale). This method gives results of measurements in units equivalent to ASTM method (ASTM D1209-05 (2011) Standard Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)). There are some small differences in the method of color comparison and equipment used. Common name Many additives have commercial names (see under label – Name). This frequently does not permit to recognize chemical composition of the additive. Common name helps in recognition of chemical nature of material. Common synonym Common synonym has similar application as the Common name. It is used to help in identification of chemical nature of the product. Daphnia magna In order to assess bioaccumulation of substance, a test organism such as Bluegill sunfish, Daphnia magna, Fathead minnow, Rainbow trout, or other is selected. The test substance is administered as a suspension directly into the water. A test organism is observed by a specified number of hours. If deleterious effects, due either to toxicity or pathogenicity, are observed, sequentially lower doses should be tested. The experiment should establish LC50 value for a particular substance and a test organism (LC50 is a dose required to kill 50 percent of the test organisms). Antistatics Databook / Copyrights 2014; ChemTec Publishing

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Davies scale Davies scale or the hydrophile-lipophile balance, HLB, is an empirical, parameter. HLB number = (hydrophilic groups) + (lipophilic groups) + 7. The HLB was originally developed as a scale to classify the relative effectiveness of nonionic surfactants at forming stable emulsions at room temperature. Surfactants with HLB values between 0 and 4 are water/oil emulsifiers, surfactants with HLB values between 6 and 10 are wetting agents, and surfactants with HLB values between 12 and 18+ are oil/water emulsifiers. Density The density, also referred to as specific weight, is the mass per volume unit in grams per cubic centimeter. The density is referred to a temperature of its determination. Dielectric constant The dielectric constant is a measure of the behavior of the substance when introduced into an electric field (it indicates the multiple to which the capacity of a condenser increases if the substance is between the plates instead of vacuum). DOT class Transportation instructions require DOT Hazard Class in which materials are divided into the following classes: 1 – Explosives, 2 – Gases, 3 – Flammable and combustible liquids, 4 – Flammable spontaneously combustible solids, 5 – Oxidizers & organic peroxides, 6 – Poisonous & infectious materials, 7 – Radioactive materials, 8 – Corrosives, 9 – Miscellaneous. In addition UN number, a packaging group is also given. Drying temperature Temperature at which drying process is conducted. Drying time Time required to dry material to a certain residual moisture at a selected drying temperature. Dropping point The ASTM dropping point is the temperature at which a grease passes from a semi-solid to a liquid state under the conditions of the test (ASTM D 566). Dropping point is expressed by a temperature of measuring gauge. EC number Number assigned by the EU commission to a substance (previously EINECS and ELINCS). The Registry of Toxic Effects of Chemical Substances (RTECS®) is a comprehensive database of basic toxicity information for over 150,000 chemical substances including: prescription and non-prescription drugs, food additives, pesticides, fungicides, herbicides, solvents, diluents, chemical wastes, reaction products of chemical waste, and substances used in both industrial and household situations. Reports of the toxic effects of each compound are cited. In addition to toxic effects and general toxicology reviews, data on skin and/or eye irritation, mutation, reproductive consequences and tumorigenicity are provided. Federal standards and regulations, NIOSH recommended exposure limits and information on the activities of the EPA, NIOSH, NTP, and OSHA regarding the substance are also included. The toxic effects are linked to literature citations from both published and unpublished governmental reports, and published articles from the scientific literature. The database corresponds to the print version of the Registry of Toxic Effects of Chemical Substances, Antistatics Databook / Copyrights 2014; ChemTec Publishing

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formerly known as the Toxic Substances List started in 1971. Originally prepared by the National Institute for Occupational Safety and Health (NIOSH), the RTECS® database is now produced and distributed by Accelrys, Inc. Empirical formula The empirical formula is the molecular formula of a chemical compound. The order of atoms follows the Hill system which is utilized by the Chemical Abstracts Services and by the Beilstein Institute. Within the empirical formula C is the first element symbol, H is the second, the other element symbols are added in alphabetical order. The empirical formula does not take into account of any crystal water content. Using this field for searches requires that the above guidelines are strictly followed. Explosive LEL The explosion limit is the lower border concentration in volume percent of a flammable gas or vapor mixed with air between which the mixture can be made to explode by heating or by a spark. Explosive UEL The explosion limit is the upper border concentration in volume percent of a flammable gas or vapor mixed with air between which the mixture can be made to explode by heating or by a spark. Eye irritation (human) The information included in this field comes from existing human experience, animal observations related to the potential irritation of human eye, and in vitro studies. Fathead minnow In order to assess bioaccumulation of substance, a test organism such as Bluegill sunfish, Daphnia magna, Fathead minnow, Rainbow trout, or other is selected. The test substance is administered as a suspension directly into the water. A test organism is observed by a specified number of hours. If deleterious effects, due either to toxicity or pathogenicity, are observed, sequentially lower doses should be tested. The experiment should establish LC50 value for a particular substance and a test organism (LC50 is a dose required to kill 50 percent of the test organisms). Features & benefits A list of features provided by an additive and benefits of its use as suggested in manufacturer’s literature. First aid Emergency treatment administered to an injured or sick person before professional medical care is available. Flash point The flash point is the lowest temperature in degrees Centigrade at which so much vapor develops under normal pressure that it results in a flammable mixture together with the air over the liquid level. Different methods are used in the test with Cleveland cup being the most suitable method for testing additives. Cleveland open cup is used to determine flash and fire points of liquids with flash point above 79oC and below 400oC, such as additives Antistatics Databook / Copyrights 2014; ChemTec Publishing

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(ASTM D92 Test Method for Flash and Fire Points by Cleveland Open Cup). Standard gives the methods of determination using manual and automatic Cleveland open cup apparatus. About 70 ml of test liquid is heated first rapidly then slowly on approaching an expected flash point. Test flame is applied to surface to ignite vapors. Test flame is natural or bottled gas flame (full description included in the standard). Test flame is applied first when the temperature is 28oC below expected flash point and then in 2oC intervals. The flash point is the lowest temperature at which vapors are ignited by the test flame. Flash point method The following abbreviations are used to describe the method that was used for the data included in the field “Flash point”: CC – closed cup, CCTC – closed cup tag closed, COC – Cleveland open cup, OC – open cup, PMCC - Pensky-Martens closed cup, TCC- tag closed cup, TOC – tag open cup Flexural modulus The ratio of outer stress to outer strain. A test specimen is held as a simply supported beam and is subjected to three-point bending. The specimen is deflected until it either breaks or the outer strain reaches 5%. ASTM D790 and ISO 178 describe full details of the method of testing. Flexural strength The maximum outer stress sustained by a specimen during testing. A test specimen is held as a simply supported beam and is subjected to three-point bending. The specimen is deflected until it either breaks or the outer strain reaches 5%. ASTM D790 and ISO 178 describe full details of the method of testing. Food approval(s) US Food and Drugs Administration, FDA, the World Health Organization, WHO, and the European Commission’s Scientific Committee on Food, SCF, must confirm that ingestion of all additives remains within safe levels. It applies to people of all ages, children as well as adults. Health consumer protection in Germany (Bundesinstitut, BgW) also examines poisonous effect of chemicals present in commercial products. Freezing point The temperature at which the liquid and solid phases of a substance of specified composition are in equilibrium at atmospheric pressure. Hazardous components Type and percentage of hazardous component present in additive. Heat of combustion It is the quantity of heat liberated per unitary weight when a substance undergoes complete oxidation. It is expressed in MJ per kg. HMIS personal protection Suggestions regarding personal protection equipment are given based on manufacturer’s recommendations.

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HMIS classification A rating system (HMIS - Hazardous Materials Identification System) has been devised by The National Paint Coatings Association to assist emergency responders. The following are the simple explanations of numerical symbols. Health: 0 – Like ordinary material, 1 – Slightly hazardous, 2 – Hazardous – use breathing apparatus, 3 – Extremely dangerous – use full protective clothing, 4 – Too dangerous to enter – vapor or liquid. Flammability: 0 – Will not burn, 1 – Must be preheated to burn, 2 – Ignites when moderately heated, 3 – Ignites at normal temperature, 4 - Extremely flammable. Reactivity: 0 – Normally stable, 1 – Unstable if heated – use normal precaution, 2 – Violent chemical change possible – use hose from distance, 3 – Strong shock or heat may detonate – use monitors, 4 – May detonate – evacuate area if materials are exposed to fire. ICAO/IATA class Classification for transport by cargo aircraft. The statements are based on the Dangerous Goods Regulation issued by IATA (International Air Transport Association). The class and the packaging group are stated. No account is taken of special regulations stipulated by individual countries or airlines. IMDG class This field contains the hazard classification for transport by sea. Impact strength, Izod notched Energy per unit thickness required to break a test specimen under flexural impact. Test specimen is held as a vertical cantilevered beam and is impacted by a swinging pendulum. The energy lost by the pendulum is equated with the energy absorbed by the test specimen. Specimen is held as a vertical cantilevered beam and is broken by a pendulum. Impact occurs on the notched side of the specimen. ASTM D256 and ISO 180 contain details of testing. Impact strength, Izod unnotched Energy per unit thickness required to break a test specimen under flexural impact. Test specimen is held as a vertical cantilevered beam and is impacted by a swinging pendulum. The energy lost by the pendulum is equated with the energy absorbed by the test specimen. Unnotched specimen is held as a vertical cantilevered beam and is broken by a pendulum. This method is covered under ASTM D4812 and ISO 180. Ingestion Ingestion is the act of taking something (food, medicine, liquid, poison, etc.) into a body through the mouth. Synonyms include “swallowing”, “taking internally”, or “eating”. Inhalation Inhalation is the drawing of air or other substances (fumes, mists, vapor, dust, etc.) into lungs (the respiratory system). Common synonym is “breathing in”. Iodine value An indication of the quantity of unsaturated fatty acids present in a fat; it represents the number of grams of iodine absorbed by 100 g of fat.

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IUPAC name International Union of Pure and Applied Chemistry, IUPAC, standardized names of organic compounds and created a systematic naming system. Kinematic viscosity A coefficient defined as the ratio of the dynamic viscosity of a fluid to its density. LC50 Lethal Concentration 50, LC50, is the concentration of a chemical which kills 50% test animal population. This measure is generally used when test animals are exposed to a test chemical in form of gas or mist. LD50 Lethal Dose 50, LD50, is the dose of a chemical which kills 50% of a sample population. In full reporting, the dose, treatment and observation period should be given. Further, LD50, LC50, ED50 and similar figures are strictly only comparable when the age, sex and nutritional state of the animals is specified. Manufacturer The name of manufacturer is given for commercial additives having a particular brand name. Melt index The amount, in grams, of a thermoplastic material which can be forced through an extrusion rheometer orifice of 0.0825 inch diameter when subjected to a force of 2160 grams in ten minutes at 190°C. Melting point The melting point is the temperature in degrees Centigrade at which the substance undergoes transition from the solid state into the liquid state. Mixture Information helps to distinguish between additives composed of a single components and mixtures of plasticizing compounds. Moisture content Moisture concentration in commercial additive as declared by its manufacturer. Mold shrinkage Shrinkage from mold cavity to molded dimensions of thermosetting plastics when molded by compression, injection, or transfer molding under specified conditions. ASTM D6289 specifies method of measurement. Molecular weight The sum of the atomic weights of all the atoms in a molecule. The weight of a molecule of any gas or vapor as compared with the hydrogen atom as a standard.

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Mutagenicity The capacity of a chemical or physical agent to cause permanent alteration of the genetic material within living cells. Tests of chemical substances and physical agents for mutagenic potential include microbial, insect, mammalian cell, and whole animal tests. Name A proper name is used, which, in the case of commercial product, is a brand name given by manufacturer and the most commonly used name in the case of generic compounds. NFPA classification A rating system has been devised by the National Fire Protection Association, NFPA, to assist emergency responders. The following are the simple explanations of numerical symbols. Health: 0 – Like ordinary material, 1 – Slightly hazardous, 2 – Hazardous – use breathing apparatus, 3 – Extremely dangerous – use full protective clothing, 4 – Too dangerous to enter – vapor or liquid. Flammability: 0 – Will not burn, 1 – Must be preheated to burn, 2 – Ignites when moderately heated, 3 – Ignites at normal temperature, 4 - Extremely flammable. Reactivity: 0 – Normally stable, 1 – Unstable if heated – use normal precaution, 2 – Violent chemical change possible – use hose from distance, 3 – Strong shock or heat may detonate – use monitors, 4 – May detonate – evacuate area if materials are exposed to fire. NIOSH REL National Institute for Occupational Safety and Health, NIOSH, recommended exposure limits (RELs) will be based on risk evaluations using human or animal health effects data, and on an assessment of what levels can be feasibly achieved by engineering controls and measured by analytical techniques. The RELs are given in either mg/m3 or ppm. Odor Any property detected by the olfactory system. In the case of chemical materials and particularly additives it helps to distinguish different materials and select non-intrusive materials for application. OSHA hazard class Occupational Safety & Health Administration, OSHA, provided a definition of hazardous and non-hazardous substances as per OSHA 29 CFR 1910.1200. OSHA PEL A Permissible Exposure Limit, PEL, is the maximum amount or concentration of a chemical that a worker may be exposed to under the U.S. Occupational Health and Safety Administration, OSHA, regulations. The PELs are given mg/m3 or ppm. Outstanding properties The most important reasons for the use of an additive are given in this field. Particle diameter A diameter of primary particle is given in nanometers. Particle length Particle length is given in microns if not otherwise specified.

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Partition coefficient The organic carbon adsorption coefficient, Koc, is only applicable for individual substances. The Koc can generally be calculated from the octanol/water partition coefficient, Kow. The following equation can be used: log Koc = 0.937 (log Kow) - 0.006. The log Kow is determined in a laboratory without the use of organisms. It is a measure of how polar the substance is by determining whether the substance partitions primarily to water or to octanol. Substances that partition primarily to octanol are likely to bioaccumulate in the fat of organisms. pH The pH value is the negative decadic logarithm of the concentration of hydrogen ions (dimensionless). Pour point The lowest temperature at which oil will pour. The pour point is the lowest temperature at which a material can be handled without excessive amounts of wax crystals forming so preventing flow. If a material is below the pour point, wax will begin to separate out which will block the filters. The wax will also build up on tank bottoms and on heating coils. Processing methods Manufacturers recommendations are given. Product contents Components of formulated products are given if available. Proper shipping name A shipping name of product as defined by the US Department of Transportation, which can be found in Hazardous Materials Table (Title CFR49). Rainbow trout In order to assess bioaccumulation of substance, a test organism such as Bluegill sunfish, Daphnia magna, Fathead minnow, Rainbow trout, or other is selected. The test substance is administered as a suspension directly into the water. A test organism is observed by a specified number of hours. If deleterious effects, due either to toxicity or pathogenicity are observed, sequentially lower doses should be tested. The experiment should establish LC50 value for a particular substance and a test organism (LC50 is a dose required to kill 50 percent of the test organisms). Recommended dosage Amount of additive recommended by its manufacturer for production of different endproducts. Recommended for products Manufacturers recommendations are given as to the product application for manufactured goods. Recommended for polymers Manufacturers recommendations are given in this field.

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Refractive index The ratio of the velocity of propagation of an electromagnetic wave in vacuum to its velocity in the medium. It is a parameter that helps to identify chemical compounds and means of their selection for use in compositions having predesigned optical properties. Refractive index has been measured at two temperatures 20 and 25oC unless otherwise indicated. Release force Release force required to separate two layers of film by an aluminum rod expressed in MPa. RTECS The Registry of Toxic Effects of Chemical Substances (RTECS®) is a comprehensive database of basic toxicity information for over 150,000 chemical substances including: prescription and non-prescription drugs, food additives, pesticides, fungicides, herbicides, solvents, diluents, chemical wastes, reaction products of chemical waste, and substances used in both industrial and household situations. Reports of the toxic effects of each compound are cited. In addition to toxic effects and general toxicology reviews, data on skin and/or eye irritation, mutation, reproductive consequences and tumorigenicity are provided. Federal standards and regulations, NIOSH recommended exposure limits and information on the activities of the EPA, NIOSH, NTP, and OSHA regarding the substance are also included. The toxic effects are linked to literature citations from both published and unpublished governmental reports, and published articles from the scientific literature. The database corresponds to the print version of the Registry of Toxic Effects of Chemical Substances, formerly known as the Toxic Substances List started in 1971. Originally prepared by the National Institute for Occupational Safety and Health (NIOSH), the RTECS® database is now produced and distributed by Accelrys, Inc. Saponification value The saponification value is the amount of alkali necessary to saponify a definite quantity of the sample. It is expressed as the number of milligrams of potassium hydroxide required to saponify 1 gram of the sample. Silicon content The fractional content of elemental silicon expressed in weight percents of total composition Skin irritation Although several mammalian species may be used, the albino rabbit is the preferred species. Exposure duration normally is four hours. Solids content The concentration of solid material in solution weight percent. Solubility in solvents A list of solvents in which material completely or partially dissolves. Solubility in water Information on solubility of additive in water.

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Specific gravity Several methods are used to determine specific gravity of the additives, such as hydrometer, digital density meter, displacement, and pycnometer methods. Specific heat The amount of heat in kilojules needed to raise the temperature of one kilogram of a substance by 1 degree of Kelvin. Specific surface area Brunauer, Emmett, and Teller (BET method) measures surface area of material based on the adsorption of gaseous nitrogen at the temperature of liquid nitrogen. For a full information how this method is carried out, one may refer to ISO 5794/1 Annex D or ASTM C1274-12. State State of additives at room temperature are contained in this field. Static decay time Time needed for a charge with a given potential (e.g., 1000 volt) to be reduced to, usually, 10% of its initial potential. Used to better characterize materials of high resistance, usually above 1010 ohm. Surface resistivity The ratio of the potential gradient parallel to the current along the surface of a material to the current per unit width of the surface. Surface resistivity is numerically equal to the surface resistance between opposite sides of a square of any size when the current flow is uniform. Surface resistivity is a general physical property of a material. It does not depend on the type of used electrodes. The physical unit of surface resistivity is ohm. Often in practice, surface resistivity is given in units of ohm/square. ASTM D257 and ISO 3915 contain details of the methods of testing. Surface resistance Surface resistance is the ratio DC voltage to the current flowing between two electrodes of specified configuration that contact the same side of a material. The unit of surface resistance is ohm. Surface resistance is a direct result of a measurement and its value depends on the used electrodes – their geometry and distance. Different kinds of electrodes would give different results for the same specimen. ASTM D257 and ISO 3915 contain details of the methods of testing. Surface tension The force acting on the surface of a liquid, tending to minimize the area of the surface; quantitatively, the force that appears to act across a line of unit length on the surface. Also known as interfacial force; interfacial tension; surface tensity. TDG class Any class as defined by Transportation of Dangerous Goods Regulations (federal) and associated provincial/territorial legislation of Canada.

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Tensile elongation Tensile elongation corresponding to the point of rupture. Testing is performed on either dumbbell, straight, or cut ring specimens. ASTM D412 and ISO 37 describe the method of testing. Tensile modulus The ratio of tensile stress to tensile strain of a material in the elastic region of a stressstrain curve. A “Tangent” tensile modulus value is the slope of the elastic region of the stress-strain curve and is also known as Young’s Modulus, or the Modulus of Elasticity. A “Secant” tensile modulus value is the slope of a line connecting the point of zero strain to a point on the stress-strain curve at a specified strain. This is used for materials that exhibit little or no linear behavior. ASTM D638 and ISO 527-1, -2 contain full description of methods of testing. Tensile strength Tensile stress corresponding to the point of rupture. Testing is performed on either dumbbell, straight, or cut ring specimens. ASTM D412 and ISO 37 describe the method of testing. Thermal conductivity The thermal conductivity, λ, is the quantity of heat transmitted, due to unit temperature gradient, in unitary time under steady conditions in a direction normal to a surface of unit area, when the heat transfer is dependent only on the temperature gradient. TLV TWA 8h The time-weighted average concentration for a conventional 8-hour workday and 40-hour workweek exposure to a substance, to which it is believed that nearly all workers may be repeatedly exposed, day after day, without adverse health effects. The data are given after American Conference of Governmental Industrial Hygienists, ACGIH, National Institute for Occupational Safety and Health, NIOSH, and Occupational Safety & Health Administration, OSHA. UN risk phrases A list of numbers of risk phrases compiled by UN which characterize behavior of a particular compound UN safety phrases A list of numbers of safety phrases compiled by UN which should be followed during transportation of a particular compound UN/NA class A four digit number representing a particular chemical or group of chemicals. These numbers are assigned by the United Nations (UN Numbers), the U.S. Department of Transportation (NA Numbers), or Transport Canada (NA Numbers). These numbers are commonly used throughout the world to aid in the quick identification of the materials contained within bulk containers (such as rail cars, semi-trailers and intermodal containers). Vapor density The density of a gas relative to the density of air. Antistatics Databook / Copyrights 2014; ChemTec Publishing

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Vapor pressure Vapor pressure is a fundamental thermodynamic property of a solid or liquid. It is the pressure generated at a particular temperature by pure component which has liquid (or solid) and vapor in equilibrium in a closed vessel. Its units are the usual units of pressure (e.g., kPa). The vapor pressure of a liquid increases with temperature between the triple point and the critical point. Viscosity It is a ratio of shear stress and shear strain expressed in mPa s. Viscosity SUS Saybolt viscosity measurement was designed for petroleum products measured at temperatures between 21 and 99C (ASTM D88-94(1999) Standard Test Method for Saybolt Viscosity). The efflux time in seconds of 60 ml samples, through a calibrated orifice, is measured. Cylindrical viscometer is immersed in thermostating bath. Measured liquid flows from viscometer into receiving flask graduated for 60 ml. The measured time in seconds is multiplied by a correction factor obtained from a measurement of viscosity standard. The result is in a Saybolt viscosity units. Viscosity temperature coefficient Viscosity of an additive (mainly silicone fluids) at 100oC divided by viscosity at 38oC. Volatility The tendency of a material to pass into the gas state at a particular temperature from a solid or liquid state, expressed in wt% loss Volume resistivity It is the resistance in ohms between opposite faces of a centimeter cube of the material tested. Its value is stated in ohms-centimeters, and it is tested as per ASTM D 257. Water solubility Solubility of additive in water.

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3 Antistatics Antistatic additives form a very diverse group of elemental, inorganic, and organic chemicals. This requires different parameters for their characterization. For this reason, tables containing characteristic parameters for a particular group differ among groups. The role of this chapter is: • to find commonalities among additives belonging to the same generic group • to show differences between different generic groups to be used as advisory tools in additive selection. Description of additives falls into one of the following categories: • general • physical properties • health and safety • ecological effect • applications. Using a standardized method of data presentation, typical characteristics of the additives are presented in a tabulated form for easy comparison.

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3.1 Organic materials 3.1.1 Amines and amides - Lauric acid diethanolamide PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Lauric acid diethanolamide

CAS #

-

Common name

Lauryl diethanolamide

Common synonym

N,N-diethanollauramide

IUPAC name

N,N-bis(2-hydroxyethyl)dodecanamide

Empirical formula

-

Formula

120-40-1

C16H33NO3

O (HOCH2CH2)2NC(CH2)10CH3

EC number

-

204-393-1

Molecular mass

daltons

287.44

Chemical category

-

amide

Moisture content

wt%

0.5

-

solid

PHYSICAL PROPERTIES State Odor

-

none

Color

-

off-white

Color, Platinum-cobalt scale

-

250 max

Boiling point

o

C

239

Melting point

o

C

38.7

Refractive index at 25 C

-

1.4708

Specific gravity at 25 C

-

1.1

Density at 25oC

kg/m3

979

Health

2

Flammability

1

Reactivity

0

o

o

HEALTH & SAFETY NFPA classification

HMIS personal protection

No specific recommendations (dust mask, neoprene or synthetic rubber gloves, eye/face protection).

UN risk phrases, R

-

38,41

UN/NA class

-

3077

Flash point

o

Flash point method

-

PMCC

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

>2000

C

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3.1 Organic materials 3.1.1 Amines and amides - Lauric acid diethanolamide PARAMETER

UNIT

VALUE

Skin irritation

May cause mild skin irritation. Prolonged or repeated contact may dry the skin. Symptoms may include redness, burning, drying and cracking of skin, and skin burns.

First aid, eyes

Rinse thoroughly with plenty of water. Eyelids should be held away from the eyeball to ensure thorough rinsing. Seek medical advice if irritation develops.

First aid, skin

Immediately take off all contaminated clothing and flush skin with large amounts of water.

First aid, inhalation

Move to fresh air. If symptoms persist, seek medical advice.

Carcinogenicity

No carcinogenic effects have been observed

Mutagenicity

Product is not considered to be genotoxic

ECOLOGICAL PROPERTIES Biodegradation probability

Biodegradable

Partition coefficient, log Kow

-

2.89 generic

USE & PERFORMANCE Manufacturer

-

Outstanding properties

Dust-free, easy dosing

Recommended for polymers

PE, PP, LDPE, HDPE, PVC, SAN, ABS

Recommended dosage

PE (0.4 to 0.8%), LDPE (0.1 to 0.5%), PBV (0.2 to 0.5%), SAN (0.5 to 1.5%), PP (0.4 to 0.8), HDPE (0.2 to 0.5%), PS (0.2 to 1.5%), ABS (0.5 to 2.5)

Processing methods

Extrusion

Additive application method

Dry-blending with other additives before adding

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Methyl bis(tallowamido ethyl) -2- hydroxyethyl ammonium methyl sulfate PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Tallow derivative

CAS #

-

68410-69-5

Empirical formula

-

C18H39NNa2O4

Mixture

-

no

EC number

-

239-032-7

Chemical category

-

amine

Color

-

off-white 3 max

PHYSICAL PROPERTIES Color, Gardner scale

-

Boiling point

o

C

Pour point

o

C

Density at 40 C o

kg/m

82.2 20 3

960

HEALTH & SAFETY NFPA classification

HMIS classification

Health

1

Flammability

3

Reactivity

0

Health

1

Flammability

3

Reactivity

0

HMIS personal protection

Chemical goggles, suitable protective clothing, and NIOSH approved respiratory protection

DOT class

-

Flash point

o

Flash point method

-

PMCC

NIOSH, TLV – TWA 8h

mg/m3

980

C

not regulated 24

ACGIH, TLV – TWA 8h

ppm

400

Animal testing, acute toxicity, Rat oral LD50

mg/kg

5045

Animal testing, acute toxicity, Mouse oral LD50

mg/kg

3600

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

12800

Animal testing, acute toxicity, Rat inhalation, LC50

mg/m3

16000 8H

Skin irritation

May cause irritation of the skin. Prolonged and/or repeated skin contact with this product may cause irritation/ dermatitis.

Eye irritation (human)

May cause irritation to the eyes

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Methyl bis(tallowamido ethyl) -2- hydroxyethyl ammonium methyl sulfate PARAMETER

UNIT

VALUE

Ingestion

Irritation of the throat, stomach, and gastrointestinal track

First aid, eyes

Flush with water for at least 15 min. Consult physician if symptoms persist.

First aid, skin

Immediately take off all contaminated clothing and flush skin with large amounts of water.

First aid, inhalation

Move victim to fresh air. If symptoms persist get medical attention. If person is not breathing apply artificial respiration or give oxygen if breathing is difficult.

Carcinogenicity

No carcinogenicity data available for this product

ECOLOGICAL PROPERTIES Biodegradation probability

Biodegradable

Aquatic toxicity, Bluegill sunfish, 96-h LC50

mg/l

0.62 to 1.2

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.3

Manufacturer

-

generic 89

USE & PERFORMANCE Concentration of active ingredients

wt%

Outstanding properties

Fabric softening, excellent cold water dispersability

Recommended for products

Household, commercial, and textile fabric

Additive application method

Immersion in dispersions containing from 2.5 to 30% solids

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Stearyl dimethyl benzyl ammonium chloride PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Steary dimethyl benzyl ammonium chloride

CAS #

-

Common name

Benzyldimethylstearylammonium chloride

122-19-0

Common synonym

Stearalkonium chloride

Empirical formula

-

C27H50ClN

Formula

Cl CH3(CH2)17NCH2

Mixture

-

yes

EC number

-

204-527-9

Molecular mass

daltons

424.16

Chemical category

-

amine

Moisture content

wt%

4

Color

-

white

Boiling point

o

PHYSICAL PROPERTIES

Density at 20 C o

C

kg/m

120 (decomp) 3

1100

HEALTH & SAFETY NFPA classification

HMIS classification

Health

2

Flammability

1

Reactivity

0

Health

2

Flammability

1

Reactivity

0

HMIS personal protection

Chemical goggles, suitable protective clothing, and NIOSH approved respiratory protection.

UN risk phrases, R

-

22,34,38,41,50

US safety phrases, S

-

26,36/37/38,45,61

UN/NA class

-

1759

DOT class

-

8 PG II

ICAO/IATA class

-

8 PG II

TDG class

-

8 PG II

Flash point

o

C

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Stearyl dimethyl benzyl ammonium chloride PARAMETER

UNIT

VALUE

Flash point method

-

PMCC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

1250

Animal testing, acute toxicity, Mouse oral LD50

mg/kg

760

Skin irritation

This product may cause irritation to the skin. Repeated or prolonged contact may be severely irritating to skin. This product is not considered a dermal sensitizing agent

Eye irritation (human)

Contact can cause moderate to severe irritation and possible injury to the eyes

Ingestion

This product may be harmful if it is swallowed

First aid, eyes

Flush with water for at least 15 min. Consult physician if symptoms persist

First aid, skin

Immediately take off all contaminated clothing and flush skin with large amounts of water

First aid, inhalation

Move victim to fresh air. If symptoms persist get medical attention. If person is not breathing apply artificial respiration or give oxygen if breathing is difficult

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

ECOLOGICAL PROPERTIES Biodegradation probability

Biodegradable

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.47

Partition coefficient, log Kow

-

3.23

Manufacturer

-

generic

Recommended for products

Hair conditioners and rinses, creams and lotions

USE & PERFORMANCE

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Hexadecyltrimethylammonium chloride PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Hexadecyltrimethylammonium chloride

CAS #

-

Common name

Cetyl trimethyl ammonium chloride

Common synonym

Cetrimonium chloride

IUPAC name

hexadecyl-trimethylammonium chloride

112-02-7

Acronym

-

CTAC

Empirical formula

-

C19H42NCl

Formula

Cl CH3(CH2)14CH2N(CH3)3

EC number

-

203-928-6

Molecular mass

daltons

320

Chemical category

-

amine

State

-

solid

Odor

-

slightly fishy

Color

-

white

Melting point

o

C

232-237

Pour point

o

C

6

PHYSICAL PROPERTIES

Refractive index at 20oC

-

1.3778

Density at 25 C

kg/m

Vapor density

-

2.07

Vapor pressure at 20oC

kPa

2.66

pH

-

4-7.5

Solubility in solvents

methanol, acetone

o

3

968

HEALTH & SAFETY NFPA classification

HMIS classification

Health

3

Flammability

1

Reactivity

0

Health

2

Flammability

1

Reactivity

0

HMIS personal protection

Chemical goggles, suitable protective clothing, and NIOSH approved respiratory protection

UN risk phrases, R

38,41,50,50/53,37/38,22,43,36/37/38

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Hexadecyltrimethylammonium chloride PARAMETER

UNIT

VALUE

US safety phrases, S

26,39,60,61,37/39,36

UN/NA class

-

3082

DOT class

-

8 III

ICAO/IATA class

-

8 III

TDG class

-

8 III

Flash point

o

Flash point method

-

PMCC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

500 to 5000

Animal testing, acute toxicity, Mouse oral LD50

mg/kg

325

Skin irritation

This product may be severely irritating to the skin. This product is not considered a dermal sensitizing

Eye irritation (human)

Contact can cause moderate to severe irritation and possible injury to the eyes

Ingestion

This product may be harmful if it is swallowed

First aid, eyes

Flush with water for at least 15 min. Consult physician if symptoms persist

First aid, skin

Immediately take off all contaminated clothing and flush skin with large amounts of water

First aid, inhalation

Move victim to fresh air. If symptoms persist get medical attention. If person is not breathing apply artificial respiration or give oxygen if breathing is difficult

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

C

93.9 max

ECOLOGICAL PROPERTIES Biodegradation probability

Biodegradable

Partition coefficient, log Kow

-

3.23

Manufacturer

-

generic

Concentration of active ingredients

wt%

>95

Recommended for products

Hair conditioners (clear or opaque), hair styling aids, creams and lotions

USE & PERFORMANCE

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Cocamidopropyl betaine PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Cocamidopropyl betaine

CAS #

-

Common name

1-Propanaminium, 3-amino-N(carboxymethyl)-N,N-dimethyl-, N-cocoacylderivatives, inner salt

61789-40-0

Empirical formula

-

C19H38N2O3

EC number

-

263-058-8

Molecular mass

daltons

342.52

Chemical category

-

amine

State

-

liquid

Color

-

clear

Boiling point

o

C

650

Melting point

o

C

283

Pour point

o

C

-5

Density at 20oC

kg/m3

1043

Density at 25 C

kg/m

1045

PHYSICAL PROPERTIES

o

3

HEALTH & SAFETY NFPA classification

HMIS classification

Health

1

Flammability

1

Reactivity

0

Health

1

Flammability

1

Reactivity

0

HMIS personal protection

Chemical goggles, suitable protective clothing, and NIOSH approved respiratory protection

DOT class

-

Flash point

o

C

not regulated none

Flash point method

-

PMCC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

5000 to 15000

Skin irritation

This products may cause irritation to the skin

Eye irritation (human)

Causes moderate eye irritation

Ingestion

Ingestion of large amounts may produce gastrointestinal disturbances including irritation, nausea, and diarrhea

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Cocamidopropyl betaine PARAMETER

UNIT

VALUE

First aid, eyes

Flush with water for at least 15 min. Consult physician if symptoms persist

First aid, skin

Immediately take off all contaminated clothing and flush skin with large amounts of water

First aid, inhalation

Move victim to fresh air. If symptoms persist get medical attention. If person is not breathing apply artificial respiration or give oxygen if breathing is difficult

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

Mutagenicity

Non-mutagenic according to Ames test

ECOLOGICAL PROPERTIES Partition coefficient, log Kow

-

0.69

Manufacturer

-

generic

Concentration of active ingredients

wt%

30

Recommended for products

Bubble baths, hand soaps, hair conditioners, cleansing creams & lotions, shampoos, shower gels, baby products, cream rinses, pet shampoos

USE & PERFORMANCE

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Dodecyltrimethyl ammonium chloride PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Dodecyltrimethyl ammonium chloride

CAS #

-

Common name

Trimethyllaurylammonium chloride

Common synonym

1-Dodecanaminium, N,N,N-trimethylchloride

112-00-5

IUPAC name

dodecyltrimethylamine chloride

Empirical formula

-

C15H34ClN

Formula

Cl CH3(CH2)10CH2N(CH3)3 EC number

-

203-927-0

Molecular mass

daltons

263.89

Chemical category

-

amine

State

-

solid

Color

colorless to light yellow

Boiling point

o

C

246 (decomp)

Melting point

o

C

237

PHYSICAL PROPERTIES

Refractive index at 20 C o

-

1.426

Tensile strength

MPa

16

Tensile elongation

%

30

Flexural modulus

MPa

1240

Mold shrinkage

%

1.2 to 1.4

Health

3

HEALTH & SAFETY NFPA classification

Flammability

3

Reactivity

0

HMIS personal protection

Face shield, full suit, respirator, gloves, boots

UN risk phrases, R

-

22,36/37/38,50/53

US safety phrases, S

-

26,29,37/39,61

UN/NA class

-

2811

ICAO/IATA class

-

III

TDG class

-

3 group II

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Dodecyltrimethyl ammonium chloride PARAMETER

UNIT

VALUE

Proper shipping name

Flammable liquid, toxic, corrosive, n.o.s. (isopropanol, quaternary ammonium salts)

Autoignition temperature

o

C

398

Flash point

o

C

19

Explosive LEL

wt%

1.8

Explosive UEL

wt%

12.8

Animal testing, acute toxicity, Rat oral LD50

mg/kg

200-1000

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

1600

Skin irritation

Harmful in contact with skin. May cause sensitization by skin contact. Moderately irritating to the skin

Eye irritation (human)

Causes moderate eye irritation

First aid, eyes

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately

First aid, skin

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention

First aid, inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

ECOLOGICAL PROPERTIES Biodegradation probability

Readily biodegradable

Aquatic toxicity, Bluegill sunfish, 96-h LC50

mg/l

1.94

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.28

Aquatic toxicity, Rainbow trout, 96-h LC50

mg/l

1 to 10

Partition coefficient, log Kow

-

1.22

Manufacturer

-

generic

Concentration of active ingredients

wt%

>98

USE & PERFORMANCE

Antistatics Databook / Copyrights 2014; ChemTec Publishing

33

Tallow bis(2-hydroxyethyl)amine PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Tallow bis(2-hydroxyethyl)amine

CAS #

-

Common name

Ethanol, 2,2’-iminobis-, N-tallow alkyl derivatives

Common synonym

Bis(2-hydroxyethyl)tallow amine

61791-44-4

Empirical formula

-

C4H11NO2

EC number

-

263-177-5

Molecular mass

daltons

105.13

Chemical category

-

amine

Moisture content

wt%

0.5

PHYSICAL PROPERTIES Odor

-

amine

Color

-

white to light yellow

Boiling point

o

C

239.4

HEALTH & SAFETY NFPA classification

Health

3

Flammability

1

Reactivity

0

HMIS personal protection

Safety glasses with side shields, NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge, body covering-clothing, neoprene or butyl rubber gloves

Food approval(s)

In polyolefin food contact films as cited in 21CFR 178.3130. Use levels are not to exceed 0.1% by weight

UN risk phrases, R

-

34

US safety phrases, S

-

26,28,36/38/39

UN/NA class

-

2735

DOT class

-

group III, class 8

ICAO/IATA class

-

group III, class 8

TDG class

-

group III, class 8

Proper shipping name

Amines, liquid, corrosive, n.o.s., 8, UN 2735, PG III, (contains ethoxylated tallow amines)

Flash point

o

Flash point method

-

COC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

600 to 1300

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

93

34

Tallow bis(2-hydroxyethyl)amine PARAMETER

UNIT

VALUE

Skin irritation

Can cause severe irritation or burns with redness, swelling, or blisters

Eye irritation (human)

Will cause eye burns and permanent tissue damage

Ingestion

May cause severe damage to mouth, throat, and stomach

First aid, eyes

Immediately flush eyes with water for at least 15 minutes. Do not let victim rub eyes. Seek medical attention immediately

First aid, inhalation

Immediately wash skin with plenty of soap and water while removing contaminated clothing and shoes. Get medical attention. Contaminated clothing should be discarded in a manner which limits further exposure

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

USE & PERFORMANCE Manufacturer

-

generic

Concentration of active ingredients

wt%

100

Outstanding properties

Easy handling, efficient, FDA approved, improves pigment dispersibility

Recommended dosage

wt%

LDPE (0.1), HDPE (0.4)

Processing methods

Extrusion, injection, and blow-molding

Additive application method

Internal

Antistatics Databook / Copyrights 2014; ChemTec Publishing

35

Soyadimethylethylammonium, ethylsulfate PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Soyadimethylethylammonium, ethylsulfate

CAS #

-

Common name

Quaternary ammonium compound

68308-67-8

EC number

-

269-663-3

Chemical category

-

amine

-

mild, characteristic

Color

-

amber

Color, Gardner scale

-

12 max

Pour point

o

PHYSICAL PROPERTIES Odor

C

50

Specific gravity at 20 C

-

1.02

pH

-

4 to 5

Health

3

Flammability

1

Reactivity

0

Health

3

Flammability

1

Reactivity

0

o

HEALTH & SAFETY NFPA classification

HMIS classification

HMIS personal protection

Gloves, coveralls, apron, boots as necessary to minimize contact. Chemical goggles; also wear a face shield if splashing hazard exists. If vapors or mists are generated, wear a NIOSH/ MSHA approved organic vapor/mist respirator or an air-supplied respirator as appropriate

UN risk phrases, R

-

36

US safety phrases, S

-

2,25,26

UN/NA class

-

1760

DOT class

-

group III, class 8

ICAO/IATA class

-

group III, class 8

Proper shipping name

Corrosive liquid, acidic, inorganic, n.o.s., (quaternary ammonium), 8, UN1760, PGIII

Flash point

o

Flash point method

-

COC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

641

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

240

36

Soyadimethylethylammonium, ethylsulfate PARAMETER

UNIT

VALUE

Skin irritation

Skin contact may cause severe damage on prolonged contact

Eye irritation (human)

Eye contact may cause severe irritation, redness, swelling, discharge or corneal clouding

First aid, eyes

Immediately rinse eyes with running water for 15 minutes. Get immediate medical attention

First aid, skin

Wash affected areas with soap and water. Remove and launder contaminated clothing before reuse. If irritation develops, get medical attention

First aid, inhalation

Move to fresh air. Aid in breathing, if necessary, and get immediate medical attention

ECOLOGICAL PROPERTIES Biodegradation probability

Not readily biodegradable

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.1 generic

USE & PERFORMANCE Manufacturer

-

Outstanding properties

Considered by manufacturer the most effective cationic antistatic; it acts as solubilizing/compatibilizing agent (it is soluble in both oil and water); it has height thermal stability (225C); high pH stability (from 2 to 11); non-corrosive

Recommended for polymers

ABS, POM, PC, PE, PP, PS, flexible and rigid PVC; synthetic fibers (acrylic, polyester, polyamide, and acetate), polyurethane foam, paints

Recommended for products

Plastics, fibers, foam, and paints

Recommended dosage

wt%

Additive application method

Internal

Antistatics Databook / Copyrights 2014; ChemTec Publishing

0.1 to 0.5

37

Hexadecyltrimethylammonium bromide PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Hexadecyltrimethylammonium bromide

CAS #

-

Common name

Cetyltrimethylammonium bromide

Common synonym

Cetrimonium bromide

Acronym

-

CTAB

Empirical formula

-

C19H42BrN

57-09-0

Formula

Br CH3(CH2)14CH2N(CH3)3 EC number

-

200-311-3

Molecular mass

daltons

364.45

Chemical category

-

amine

State

-

solid

Odor

-

odorless

Color

-

white

Melting point

o

C

Freezing point

o

C

Bulk density

kg/m

pH

-

4 to 6

g/l

19

UN risk phrases, R

-

22,36/37/38,50/53

US safety phrases, S

-

26,37/39,61

DOT class

-

9 III

ICAO/IATA class

-

9 III

TDG class

-

9 III

Proper shipping name

Corrosive solid, ACJDJC, ORGANIC

Flash point

o

Animal testing, acute toxicity, Rat oral LD50

mg/kg

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

PHYSICAL PROPERTIES

Solubility in water at 25 C o

248-250 244 3

500

HEALTH & SAFETY

C

244 410

ECOLOGICAL PROPERTIES Partition coefficient, log Koc

-

Antistatics Databook / Copyrights 2014; ChemTec Publishing

3.18

38

Hexadecyltrimethylammonium bromide PARAMETER

UNIT

VALUE

Manufacturer

-

generic

Concentration of active ingredients

wt%

100

Recommended for products

Hair conditioner

USE & PERFORMANCE

Antistatics Databook / Copyrights 2014; ChemTec Publishing

39

Accosoft 440-75 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Accosoft 440-75

CAS #

-

Common name

Methyl bis(hydrogenated tallow amidoethyl)-2-hydroxyethyl ammonium methyl sulfate

Common synonym

Hydrogenated tallow

Mixture

-

no

Chemical category

-

amine

Color

-

off-white

Color, Gardner scale

-

4 max

Boiling point

o

C

82.2

Pour point

o

C

45

Density at 40oC

kg/m3

68389-89-9

PHYSICAL PROPERTIES

840

pH

-

6

Viscosity at 25oC

mPas

1200

Health

1

Flammability

3

Reactivity

0

Health

1

Flammability

3

Reactivity

0

HEALTH & SAFETY NFPA classification

HMIS classification

HMIS personal protection

Chemical goggles, suitable protective clothing, and NIOSH approved respiratory protection

DOT class

-

Hazardous ingredients

15% isopropanol

Flash point

o

Flash point method

-

PMCC

NIOSH, TLV – TWA 8h

mg/m3

980

ACGIH, TLV – TWA 8h

ppm

400

NIOSH, TLV – TWA 8h

ppm

400

Animal testing, acute toxicity, Rat oral LD50

mg/kg

5000 to 15000

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

20000

Animal testing, acute toxicity, Rat inhalation, LC50

ppm

16000 8H

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

not regulated 24

40

Accosoft 440-75 PARAMETER

UNIT

VALUE

Skin irritation

May cause irritation of the skin but it is not considered a dermal sensitizing agent

Eye irritation (human)

May cause irritation to the eyes

Ingestion

Irritation of the throat, stomach, and gastrointestinal track

Chronic effects First aid, eyes

Flush with water for at least 15 min. Consult physician if symptoms persist

First aid, skin

Immediately take off all contaminated clothing and flush skin with large amounts of water

First aid, inhalation

Move victim to fresh air. If symptoms persist get medical attention. If person is not breathing apply artificial respiration or give oxygen if breathing is difficult

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

Mutagenicity

Non-mutagenic according to Ames test

ECOLOGICAL PROPERTIES Biodegradation probability

Biodegradable

Aquatic toxicity, Bluegill sunfish, 96-h LC50

mg/l

0.62 to 1.2

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.3

Manufacturer

-

Stepan Company 75

USE & PERFORMANCE Concentration of active ingredients

wt%

Outstanding properties

Fabric softening, does not cause fabric to yellow

Recommended for products

Household, commercial, and textile fabric

Additive application method

Immersion in dispersions containing up to 8% solids

Antistatics Databook / Copyrights 2014; ChemTec Publishing

41

Accosoft 750 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Accosoft 750

CAS #

-

Common name

Methyl bis(soya amidoethyl)-2-hydroxyethyl quaternary ammonium methyl sulfate

Common synonym

Soya derivative

Mixture

-

no

Chemical category

-

amine

Color

-

yellow

Color, Gardner scale

-

7 max

Boiling point

o

C

82.2

Pour point

o

C

10

Density at 40oC

kg/m3

70914-09-9

PHYSICAL PROPERTIES

960

pH

-

6

Viscosity at 25oC

mPas

2000

Health

1

Flammability

3

Reactivity

0

Health

1

Flammability

3

Reactivity

0

HEALTH & SAFETY NFPA classification

HMIS classification

HMIS personal protection

Chemical goggles, suitable protective clothing, and NIOSH approved respiratory protection

DOT class

-

Hazardous ingredients

10% isopropanol

Flash point

o

Flash point method

-

PMCC

NIOSH, TLV – TWA 8h

mg/m3

980

ACGIH, TLV – TWA 8h

ppm

400

NIOSH, TLV – TWA 8h

ppm

400

Animal testing, acute toxicity, Rat oral LD50

mg/kg

16000

Animal testing, acute toxicity, Mouse oral LD50

mg/kg

3600

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

12800

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

not regulated 22

42

Accosoft 750 PARAMETER

UNIT

VALUE

Animal testing, acute toxicity, Rat inhalation, LC50

ppm

16000 8H

Skin irritation

May cause irritation of the skin but it is not considered a dermal sensitizing agent

Eye irritation (human)

May cause irritation to the eyes

Ingestion

Irritation of the throat, stomach, and gastrointestinal track

First aid, eyes

Flush with water for at least 15 min. Consult physician if symptoms persist

First aid, skin

Immediately take off all contaminated clothing and flush skin with large amounts of water

First aid, inhalation

Move victim to fresh air. If symptoms persist get medical attention. If person is not breathing apply artificial respiration or give oxygen if breathing is difficult

Carcinogenicity

ACGIH - A4 (not classifiable as human carcinogen), IARC - group 1, supplement 7, 1987 (carcinogenic to human) (isopropanol) final product not known

ECOLOGICAL PROPERTIES Biodegradation probability

Biodegradable

Aquatic toxicity, Bluegill sunfish, 96-h LC50

mg/l

0.62 to 1.2

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.3

Manufacturer

-

Stepan Company

Concentration of active ingredients

wt%

90

Outstanding properties

Fabric softening and controlling static cling

Recommended for products

Household and textiles

Additive application method

During wash cycle in combination with nonionic surfactant

USE & PERFORMANCE

Antistatics Databook / Copyrights 2014; ChemTec Publishing

43

Accosoft 780 PG PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Accosoft 780 PG

CAS #

-

Common name

Methyl bis(canola amidoethyl)-2-hydroxyethyl ammonium methyl sulfate

Common synonym

Canola derivative

70914-09-9

Mixture

-

no

Chemical category

-

amine

Color

-

yellow

Color, Gardner scale

-

4 max

Boiling point

o

C

Pour point

o

C

Specific gravity at 20oC

-

0.95

Density at 40oC

kg/m3

950

PHYSICAL PROPERTIES

110 12

pH

-

6

Viscosity at 25oC

mPas

5000

Health

1

Flammability

1

Reactivity

0

Health

1

Flammability

1

Reactivity

0

HEALTH & SAFETY NFPA classification

HMIS classification

HMIS personal protection

Chemical goggles, suitable protective clothing, and NIOSH approved respiratory protection

DOT class

-

Hazardous ingredients

10% propylene glycol

Flash point

o

Flash point method

-

PMCC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

15000

Animal testing, acute toxicity, Mouse oral LD50

mg/kg

22000

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

20800

Skin irritation

May cause irritation of the skin but it is not considered a dermal sensitizing agent

Eye irritation (human)

May cause irritation to the eyes

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

not regulated 93.9

44

Accosoft 780 PG PARAMETER

UNIT

VALUE

Ingestion

Irritation of the throat, stomach, and gastrointestinal track

First aid, eyes

Flush with water for at least 15 min. Consult physician if symptoms persist

First aid, skin

Immediately take off all contaminated clothing and flush skin with large amounts of water

First aid, inhalation

Move victim to fresh air. If symptoms persist get medical attention. If person is not breathing apply artificial respiration or give oxygen if breathing is difficult

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

ECOLOGICAL PROPERTIES Biodegradation probability

Biodegradable

Aquatic toxicity, Bluegill sunfish, 96-h LC50

mg/l

0.62 to 1.2

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.3

Manufacturer

-

Stepan Company

Concentration of active ingredients

wt%

90

Outstanding properties

Fabric softening and controlling static cling

USE & PERFORMANCE

Recommended for products

Household and textiles

Additive application method

During wash cycle in combination with nonionic surfactant

Antistatics Databook / Copyrights 2014; ChemTec Publishing

45

Accosoft 808 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Accosoft 808

CAS #

-

Common name

Methyl (1) tallow amidoethyl (2) tallow imidazolinium methyl sulfate

Common synonym

Tallow derivative

68122-86-1

Mixture

-

no

Chemical category

-

amine

Color

-

yellow

Color, Gardner scale

-

6 max

Boiling point

o

C

82.2

Pour point

o

C

10

Density at 40oC

kg/m3

910

pH

-

6

mPas

1500

Health

1

PHYSICAL PROPERTIES

Viscosity at 25 C o

HEALTH & SAFETY NFPA classification

HMIS classification

Flammability

3

Reactivity

0

Health

1

Flammability

3

Reactivity

0

HMIS personal protection

Chemical goggles, suitable protective clothing, and NIOSH approved respiratory protection

DOT class

-

Hazardous ingredients

20% propylene glycol

Flash point

o

Flash point method

-

PMCC

NIOSH, TLV – TWA 8h

mg/m3

980

ACGIH, TLV – TWA 8h

ppm

400

C

not regulated 23.5

NIOSH, TLV – TWA 8h

ppm

400

Animal testing, acute toxicity, Rat oral LD50

mg/kg

21600

Animal testing, acute toxicity, Mouse oral LD50

mg/kg

3600

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

12800

Antistatics Databook / Copyrights 2014; ChemTec Publishing

46

Accosoft 808 PARAMETER

UNIT

VALUE

Animal testing, acute toxicity, Rat inhalation, LC50

ppm

16000 8H

Skin irritation

May cause irritation of the skin but it is not considered a dermal sensitizing agent

Eye irritation (human)

May cause irritation to the eyes

Ingestion

Irritation of the throat, stomach, and gastrointestinal track

First aid, eyes

Flush with water for at least 15 min. Consult physician if symptoms persist

First aid, skin

Immediately take off all contaminated clothing and flush skin with large amounts of water

First aid, inhalation

Move victim to fresh air. If symptoms persist get medical attention. If person is not breathing apply artificial respiration or give oxygen if breathing is difficult

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

Mutagenicity

Non-mutagenic according to Ames test

ECOLOGICAL PROPERTIES Biodegradation probability

Biodegradable

Aquatic toxicity, Bluegill sunfish, 96-h LC50

mg/l

0.62 to 1.2

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.3

USE & PERFORMANCE Manufacturer

-

Stepan Company

Concentration of active ingredients

wt%

80

Outstanding properties

Fabric softening and controlling static cling

Recommended for products

Household and textiles

Additive application method

Immersion in dispersions

Antistatics Databook / Copyrights 2014; ChemTec Publishing

47

Ammonyx 4 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ammonyx 4

CAS #

-

Common name

Stearyl dimethyl benzyl ammonium chloride

Common synonym

Stearalkonium chloride

122-19-0

Formula

Cl CH3(CH2)17NCH2

Mixture

-

yes

EC number

-

204-527-9

Chemical category

-

amine

Color

-

yellow

Boiling point

o

PHYSICAL PROPERTIES

Density at 20 C o

C

kg/m

120 3

985

pH

-

3.77

Izod impact notched

J/m

214

Izod impact unnoched

J/m

no break

Tensile strength

MPa

41

Tensile elongation

%

10 min

Tensile modulus

MPa

1931

Flexural strength

MPa

69

Flexural modulus

MPa

2137

Mold shrinkage

%

0.6 to 0.8

Drying time

h

2

Drying temperature

o

C

82

HEALTH & SAFETY NFPA classification

HMIS classification

HMIS personal protection

Health

2

Flammability

1

Reactivity

0

Health

2

Flammability

1

Reactivity

0

Chemical goggles, suitable protective clothing, and NIOSH approved respiratory protection

Antistatics Databook / Copyrights 2014; ChemTec Publishing

48

Ammonyx 4 PARAMETER

UNIT

VALUE not regulated

DOT class

-

Flash point

o

Flash point method

-

C

93.9 PMCC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

500 to 5000

Animal testing, acute toxicity, Mouse oral LD50

mg/kg

760

Skin irritation

This product may cause irritation to the skin. Repeated or prolonged contact may cause severe irritation. This product is not considered a dermal sensitizing agent

Eye irritation (human)

Contact can cause moderate to severe irritation and possible injury to the eyes

Ingestion

This product may be harmful if it is swallowed

First aid, eyes

Flush with water for at least 15 min. Consult physician if symptoms persist

First aid, skin

Immediately take off all contaminated clothing and flush skin with large amounts of water

First aid, inhalation

Move victim to fresh air. If symptoms persist get medical attention. If person is not breathing apply artificial respiration or give oxygen if breathing is difficult

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

ECOLOGICAL PROPERTIES Biodegradation probability

Biodegradable

Partition coefficient, log Kow

-

5.87

Manufacturer

-

Stepan Company

Concentration of active ingredients

wt%

18.6

Recommended for products

Conditioners, cream rinses, mousses and lotions; performs as an emollient as well as a conditioning and antistatic agent

Features & benefits

Antistatic properties eliminate combing problems and give a smooth feel to hair

USE & PERFORMANCE

Antistatics Databook / Copyrights 2014; ChemTec Publishing

49

Ammonyx CDO special PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ammonyx CDO special

CAS #

-

Common name

Cocoamidopropylamine oxide

Mixture

-

yes

EC number

-

268-938-5

Chemical category

-

amine

Color

-

light straw colored

Boiling point

o

C

100

Pour point

o

C

-4

Density at 20oC

kg/m3

68155-09-9

PHYSICAL PROPERTIES

1020

pH

-

7.9

Viscosity at 25oC

mPas

45

Izod impact notched

J/m

160

Izod impact unnoched

J/m

1335

Tensile strength

MPa

31

Tensile elongation

%

10 min

Tensile modulus

MPa

1448

Flexural strength

MPa

54

Flexural modulus

MPa

1655

Mold shrinkage

%

0.5 to 0.7

Drying time

h

2

Drying temperature

o

C

82

HEALTH & SAFETY NFPA classification

HMIS classification

Health

1

Flammability

1

Reactivity

0

Health

1

Flammability

1

Reactivity

0

HMIS personal protection

Chemical goggles, suitable protective clothing, and NIOSH approved respiratory protection

DOT class

-

Flash point

o

Flash point method

-

PMCC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

500 to 5000

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

not regulated 93.9

50

Ammonyx CDO special PARAMETER

UNIT

VALUE

Skin irritation

Prolonged contact may results in mild irritation or redness

Eye irritation (human)

This product may cause irritation to the eyes

Ingestion

Ingestion of large amounts may produce gastrointestinal disturbances including irritation, nausea, and diarrhea

Chronic effects First aid, eyes

Flush with water for at least 15 min. Consult physician if symptoms persist

First aid, skin

Immediately take off all contaminated clothing and flush skin with large amounts of water

First aid, inhalation

Move victim to fresh air. If symptoms persist get medical attention. If person is not breathing apply artificial respiration or give oxygen if breathing is difficult

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

ECOLOGICAL PROPERTIES Biodegradation probability

Biodegradable

USE & PERFORMANCE Manufacturer

-

Recommended for products

Shampoos, creams and lotions, hand soaps, wax strippers, bubble baths, allpurpose cleansers

Antistatics Databook / Copyrights 2014; ChemTec Publishing

Stepan Company

51

Ammonyx CETAC PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ammonyx CETAC

CAS #

-

Common name

Cetyl trimethyl ammonium chloride

Common synonym

Cetrimonium chloride

Empirical formula

-

Formula

112-02-7

C19H42NCl

Cl CH3(CH2)14CH2N(CH3)3

EC number

-

203-928-6

Molecular mass

daltons

319

Chemical category

-

amine

Color

-

pale yellow

Boiling point

o

C

100

Pour point

o

C

6

Density at 20oC

kg/m3

PHYSICAL PROPERTIES

932

pH

-

3.8

Viscosity at 25oC

mPas

6

Izod impact notched

J/m

43

Izod impact unnoched

J/m

267

Tensile strength

MPa

41

Tensile elongation

%

3 to 5

Tensile modulus

MPa

3103

Flexural strength

MPa

76

Flexural modulus

MPa

3103

Mold shrinkage

%

0.2 to 0.4

Drying time

h

2

Drying temperature

o

C

82

HEALTH & SAFETY NFPA classification

HMIS classification

Health

2

Flammability

1

Reactivity

0

Health

2

Flammability

1

Reactivity

0

Antistatics Databook / Copyrights 2014; ChemTec Publishing

52

Ammonyx CETAC PARAMETER

UNIT

VALUE

HMIS personal protection

Chemical goggles, suitable protective clothing, and NIOSH approved respiratory protection

DOT class

-

Flash point

o

Flash point method

-

PMCC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

500 to 5000

Skin irritation

This product may be severely irritating to the skin. This product is not considered a dermal sensitizing

Eye irritation (human)

Contact can cause moderate to severe irritation and possible injury to the eyes

Ingestion

Contact can cause moderate to severe irritation and possible injury to the eyes

C

not regulated 93.9

Chronic effects First aid, eyes

Flush with water for at least 15 min. Consult physician if symptoms persist.

First aid, skin

Immediately take off all contaminated clothing and flush skin with large amounts of water

First aid, inhalation

Move victim to fresh air. If symptoms persist get medical attention. If person is not breathing apply artificial respiration or give oxygen if breathing is difficult

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

ECOLOGICAL PROPERTIES Biodegradation probability

Biodegradable

Partition coefficient, log Kow

-

3.18

Manufacturer

-

Stepan Company

Recommended for products

Hair conditioners (clear or opaque), hair styling aids, creams and lotions

USE & PERFORMANCE

Antistatics Databook / Copyrights 2014; ChemTec Publishing

53

Ammonyx KP PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ammonyx KP

CAS #

-

Common name

Oleyl dimethylamine ammonium chloride

Common synonym

Olealkonium chloride

Empirical formula

-

37139-99-4

C27H48NCl

Formula Cl CH3(CH2)7CH CH(CH2)8NCH2

EC number

-

253-363-4

Molecular mass

daltons

422.14

Chemical category

-

amine

Color

-

clear

Boiling point

o

Density at 20oC

kg/m3

983

pH

-

4.8

Izod impact notched

J/m

107

Izod impact unnoched

J/m

no break

PHYSICAL PROPERTIES C

100

Tensile strength

MPa

43

Tensile elongation

%

10 min

Tensile modulus

MPa

1379

Flexural strength

MPa

55

Flexural modulus

MPa

1724

Mold shrinkage

%

1.8 to 2.5

Drying time

h

2

Drying temperature

o

C

121

HEALTH & SAFETY NFPA classification

HMIS classification

HMIS personal protection

Health

2

Flammability

1

Reactivity

0

Health

2

Flammability

1

Reactivity

0

Chemical goggles, suitable protective clothing, and NIOSH approved respiratory protection

Antistatics Databook / Copyrights 2014; ChemTec Publishing

54

Ammonyx KP PARAMETER

UNIT

VALUE not regulated

DOT class

-

Flash point

o

Flash point method

-

Skin irritation

This product may be severely irritating to the skin. This product is not considered a dermal sensitizing

Eye irritation (human)

Contact can cause moderate to severe irritation and possible injury to the eyes

Ingestion

This product may be harmful if it is swallowed

First aid, eyes

Flush with water for at least 15 min. Consult physician if symptoms persist.

First aid, skin

Immediately take off all contaminated clothing and flush skin with large amounts of water

First aid, inhalation

Move victim to fresh air. If symptoms persist get medical attention. If person is not breathing apply artificial respiration or give oxygen if breathing is difficult

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

C

93.9 PMCC

Mutagenicity

ECOLOGICAL PROPERTIES Biodegradation probability

Biodegradable

Partition coefficient, log Kow

-

5.66

Manufacturer

-

Stepan Company

Concentration of active ingredients

wt%

50

Recommended for products

Clear leave-on hair conditioners, hair conditioners/cream rinses, hair mousses, skin lotions

USE & PERFORMANCE

Antistatics Databook / Copyrights 2014; ChemTec Publishing

55

Amphosol CA PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Amphosol CA

CAS #

-

Common name

Cocamidopropyl betaine

EC number

-

263-058-8

Chemical category

-

amine

Color

-

clear

Boiling point

o

C

100 max

Melting point

o

C

-8

Pour point

o

C

61789-40-0

PHYSICAL PROPERTIES

Density at 20 C o

kg/m

-5 3

1043

pH

-

4 to 6

Viscosity at 25oC

mPas

16

Izod impact notched

J/m

80

Izod impact unnoched

J/m

427

Tensile strength

MPa

55

Tensile elongation

%

3 to 5

Tensile modulus

MPa

3448

Flexural strength

MPa

83

Flexural modulus

MPa

3448

Mold shrinkage

%

0.4 to 0.7

Drying time

h

2

Drying temperature

o

C

121

HEALTH & SAFETY NFPA classification

HMIS classification

Health

1

Flammability

1

Reactivity

0

Health

1

Flammability

1

Reactivity

0

HMIS personal protection

Chemical goggles, suitable protective clothing, and NIOSH approved respiratory protection

DOT class

-

Flash point

o

Flash point method

-

PMCC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

5000 to 15000

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

not regulated 93.9

56

Amphosol CA PARAMETER

UNIT

VALUE

Skin irritation

This products may cause irritation to the skin

Eye irritation (human)

Causes moderate eye irritation

Ingestion

Ingestion of large amounts may produce gastrointestinal disturbances including irritation, nausea, and diarrhea

First aid, eyes

Flush with water for at least 15 min. Consult physician if symptoms persist.

First aid, skin

Immediately take off all contaminated clothing and flush skin with large amounts of water

First aid, inhalation

Move victim to fresh air. If symptoms persist get medical attention. If person is not breathing apply artificial respiration or give oxygen if breathing is difficult

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

Mutagenicity

Non-mutagenic according to Ames test

ECOLOGICAL PROPERTIES Biodegradation probability

Biodegradable

USE & PERFORMANCE Manufacturer

-

Stepan Company

Concentration of active ingredients

wt%

30

Recommended for products

Bubble baths, hand soaps, hair conditioners, cleansing creams & lotions, shampoos, shower gels, baby products, cream rinses, pet shampoos

Antistatics Databook / Copyrights 2014; ChemTec Publishing

57

Amphosol LB PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Amphosol LB

CAS #

-

Common name

Laurylamidopropyl betaine

Formula

4292-10-8

O CH3(CH2)10CN(CH2)3)NCH2CO O

H EC number

-

224-292-6

Chemical category

-

amine

Color

-

clear

Boiling point

o

C

100 max

Melting point

o

C

-3

Density at 20oC

kg/m3

PHYSICAL PROPERTIES

1043

pH

-

8

Viscosity at 25oC

mPas

12.6

Tensile strength

MPa

10

Tensile elongation

%

1500 min

Drying time

h

6

Drying temperature

o

C

107

HEALTH & SAFETY NFPA classification

HMIS classification

Health

1

Flammability

1

Reactivity

0

Health

1

Flammability

1

Reactivity

0

HMIS personal protection

Chemical goggles, suitable protective clothing, and NIOSH approved respiratory protection

DOT class

-

Flash point

o

Flash point method

-

PMCC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

5000 to 15000

Skin irritation

This products may cause irritation to the skin

Eye irritation (human)

Causes moderate eye irritation

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

not regulated 93.9

58

Amphosol LB PARAMETER

UNIT

VALUE

Ingestion

Ingestion of large amounts may produce gastrointestinal disturbances including irritation, nausea, and diarrhea

First aid, eyes

Flush with water for at least 15 min. Consult physician if symptoms persist.

First aid, skin

Immediately take off all contaminated clothing and flush skin with large amounts of water

First aid, inhalation

Move victim to fresh air. If symptoms persist get medical attention. If person is not breathing apply artificial respiration or give oxygen if breathing is difficult

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

Mutagenicity

Non-mutagenic according to Ames test

ECOLOGICAL PROPERTIES Biodegradation probability

Biodegradable

Partition coefficient, log Kow

-

0.69

USE & PERFORMANCE Manufacturer

-

Stepan Company

Concentration of active ingredients

wt%

30

Recommended for products

Electronics, optics

Antistatics Databook / Copyrights 2014; ChemTec Publishing

59

Armac C PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Armac C

Common name

Cocoalkylamine acetates

Chemical category

-

amine

Moisture content

wt%

2 10 max

PHYSICAL PROPERTIES Color, Gardner scale

-

Melting point

o

C

Pour point

o

C

50 55

Density at 20 C

kg/m

Viscosity at 25oC

mPas

20

Solubility in water at 25oC

g/l

soluble

Solubility in solvents

isopropanol, benzene

Tensile strength

MPa

4

Tensile elongation

%

450 min

o

3

852

Mold shrinkage

%

1.0 to 2.0

Drying time

h

2

Drying temperature

o

C

79

USE & PERFORMANCE Manufacturer

-

Antistatics Databook / Copyrights 2014; ChemTec Publishing

AKZO Nobel

60

Armac HT PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Armac HT

Common name

Hydrogenated tallowalkylamine acetates

Chemical category

-

amine

Moisture content

wt%

2 10 max

PHYSICAL PROPERTIES Color, Gardner scale

-

Boiling point

o

C

100

Melting point

o

C

60

Pour point

o

C

70

Density at 20oC

kg/m3

820

kPa

0.13 max

Vapor pressure at 20 C o

pH

-

6 to 9

Izod impact notched

J/m

53

Izod impact unnoched

J/m

641

Tensile strength

MPa

30

Tensile elongation

%

10 min

Tensile modulus

MPa

1793

Flexural strength

MPa

41

Flexural modulus

MPa

1655

Mold shrinkage

%

1.8 to 2.4

-

AKZO Nobel

USE & PERFORMANCE Manufacturer

Antistatics Databook / Copyrights 2014; ChemTec Publishing

61

Armac T PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Armac T

CAS #

-

Common name

Amines, tallow alkyl, acetates

Common synonym

Tallowalkylamine acetates

EC number

-

263-150-8

Chemical category

-

amine

Moisture content

wt%

2

61790-60-1

PHYSICAL PROPERTIES Odor

-

acetic acid

Color

-

yellow

Color, Gardner scale

-

10 max

Melting point

o

C

Pour point

o

C

Density at 20 C

kg/m

o

55 65 3

845

Vapor pressure at 20 C

kPa

0.01 max

pH

-

6 to 9 soluble

o

Solubility in water at 25 C

g/l

Solubility in solvents

isopropanol, ethanol, hexane

Izod impact notched

J/m

214

Izod impact unnoched

J/m

no break

Tensile strength

MPa

21

Tensile elongation

%

10 min

o

Tensile modulus

MPa

827

Flexural strength

MPa

30

Flexural modulus

MPa

1034

Mold shrinkage

%

1.8 to 2.2

Health

3

HEALTH & SAFETY NFPA classification

HMIS classification

Flammability

1

Reactivity

0

Health

3

Flammability

1

Reactivity

0

HMIS personal protection

Splash goggles, synthetic apron, vapor respirator, and gloves

UN/NA class

-

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1759 62

Armac T PARAMETER

UNIT

VALUE

DOT class

-

group III, class 8

ICAO/IATA class

-

group III, class 8

TDG class

-

group III, class 8

Proper shipping name

Corrosive solids, n.o.s. (fatty amine acetates)

Flash point

o

Flash point method

-

PMCC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

2000 max

Skin irritation

Corrosive to the skin

Eye irritation (human)

Corrosive to the eyes

First aid, eyes

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately

First aid, skin

Wash with soap and water. Get medical attention if irritation develops. Cold water may be used

First aid, inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear

Carcinogenicity

IARC, NTP, OSHA, ACGIH: Not listed

Mutagenicity

None

C

149

ECOLOGICAL PROPERTIES Aquatic toxicity, Bluegill sunfish, 96-h LC50

mg/l

0.11

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.011

Manufacturer

-

AKZO Nobel

Davis scale

-

6.8

Concentration of active ingredients

wt%

95-100

USE & PERFORMANCE

Antistatics Databook / Copyrights 2014; ChemTec Publishing

63

Armostat 1800 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Armostat 1800

CAS #

-

Common name

Alkyl(C16-C18)bis(2-hydroxyethyl) amine

Common synonym

Octadecylbis(2-hydroxyethyl) amine

IUPAC name

2-[(2-hydroxyethyl)octadecylamino] ethan-1-ol

Empirical formula

-

EC number

-

233-520-3

Molecular mass

daltons

357.62

Chemical category

-

amine

Moisture content

wt%

0.3

Color

-

yellowish

Color, Platinum-cobalt scale

-

150 max

Melting point

o

C

Pour point

o

C

10213-78-2

C22H47NO2

PHYSICAL PROPERTIES

52.2 55

Density at 20 C

kg/m

Solubility in water at 25oC

g/l

practically insoluble

Izod impact notched

J/m

320

Izod impact unnoched

J/m

no break

Tensile strength

MPa

7

o

3

1000

Tensile elongation

%

10 min

Tensile modulus

MPa

207

Flexural strength

MPa

7

Flexural modulus

MPa

207

Mold shrinkage

%

1.8 to 2.2

Health

3

Flammability

1

Reactivity

0

HEALTH & SAFETY HMIS classification

HMIS personal protection

No specific recommendations (dust mask, neoprene or synthetic rubber gloves, eye/face protection)

DOT class

-

group III, class 8

ICAO/IATA class

-

group III, class 8

Antistatics Databook / Copyrights 2014; ChemTec Publishing

64

Armostat 1800 PARAMETER

UNIT

Proper shipping name

Corrosive solids, n.o.s. (fatty amine acetates)

Flash point

o

Flash point method

-

First aid, eyes

Rinse thoroughly with plenty of water. Eyelids should be held away from the eyeball to ensure thorough rinsing. Seek medical advice if irritation develops

First aid, skin

Immediately take off all contaminated clothing and flush skin with large amounts of water.

First aid, inhalation

Immediately take off all contaminated clothing and flush skin with large amounts of water.

C

VALUE

204 min COC

ECOLOGICAL PROPERTIES Biodegradation probability

Biodegradable

Partition coefficient, log Kow

-

6.85

Manufacturer

-

AKZO Nobel

Outstanding properties

Excellent thermal stability due to its saturated structure; good for higher processing temperatures

Recommended for polymers

PE, LLDPE, PP, SAN and ABS

Recommended dosage

PE, PP (0.1 to 0.3%) ABS (1.5 to 3%)

Features & benefits

Pigment or color concentrates should be mixed with the antistatic agent prior to extruding. Premixing ensures uniform distribution of Armostat 1800 in the resin while Armostat 1800 acts as a dispersion aid to the pigment color concentrate

Processing methods

Single or twin-screw extruders

USE & PERFORMANCE

Antistatics Databook / Copyrights 2014; ChemTec Publishing

65

Armostat 2000 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Armostat 2000

CAS #

-

Common name

Lauric diethanol amide

IUPAC name

N,N-bis(2-hydroxyethyl)dodecanamide

Empirical formula

-

Formula

120-40-1

C16H33NO3

O (HOCH2CH2)2NC(CH2)10CH3

EC number

-

204-393-1

Molecular mass

daltons

287.44

Chemical category

-

amine

Moisture content

wt%

0.5

Color

-

off-white

Color, Platinum-cobalt scale

-

250 max

Melting point

o

PHYSICAL PROPERTIES

C

45

Density at 20 C

kg/m

Solubility in water at 25oC

g/l

practically insoluble

Izod impact notched

J/m

53

Izod impact unnoched

J/m

534

Tensile strength

MPa

15

Tensile elongation

%

6 to 10

o

3

960

Tensile modulus

MPa

1517

Flexural strength

MPa

30

Flexural modulus

MPa

1241

Mold shrinkage

%

1.0 to 1.5

Drying time

h

2

Drying temperature

o

C

79

HEALTH & SAFETY NFPA classification

Health

2

Flammability

1

Reactivity

0

HMIS personal protection

No specific recommendations (dust mask, neoprene or synthetic rubber gloves, eye/face protection)

UN risk phrases, R

-

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36/38 66

Armostat 2000 PARAMETER

UNIT

Proper shipping name

Corrosive solids, n.o.s. (fatty amine acetates)

Flash point

o

Flash point method

-

First aid, eyes

Rinse thoroughly with plenty of water. Eyelids should be held away from the eyeball to ensure thorough rinsing. Seek medical advice if irritation develops

First aid, skin

Immediately take off all contaminated clothing and flush skin with large amounts of water.

First aid, inhalation

Immediately take off all contaminated clothing and flush skin with large amounts of water.

C

VALUE

180 PMCC

ECOLOGICAL PROPERTIES Biodegradation probability

Biodegradable

Partition coefficient, log Kow

-

2.89

Manufacturer

-

AKZO Nobel

Outstanding properties

Dust free easy dosing

Recommended for polymers

PE, PP, LDPE, HDPE, PVC, SAN, ABS

Recommended dosage

PE (0.4 to 0.8%), LDPE (0.1 to 0.5%), PBV (0.2 to 0.5%), SAN (0.5 to 1.5%), PP (0.4 to 0.8), HDPE (0.2 to 0.5%), PS (0.2 to 1.5%), ABS (0.5 to 2.5)

USE & PERFORMANCE

Processing methods

Extrusion

Additive application method

Dry-blending with other additives before adding

Antistatics Databook / Copyrights 2014; ChemTec Publishing

67

Armostat 400 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Armostat 400

CAS #

-

Common name

Alkyl(C12-C14)bis(2-hydroxyethyl)amine

Common synonym

Cocobis(2-hydroxyethyl)amine

EC number

-

263-163-9

Molecular mass

daltons

275 to 300

Chemical category

-

amine

Moisture content

wt%

0.5

Color

-

almost colorless

Color, Platinum-cobalt scale

-

150 max

Melting point

o

Density at 20oC

kg/m3

910

mPas

150

61791-31-9

PHYSICAL PROPERTIES

Viscosity at 20 C o

C

-1

Solubility in water at 25 C

g/l

practically insoluble

Izod impact notched

J/m

no break

Izod impact unnoched

J/m

no break

Tensile strength

MPa

25

Tensile elongation

%

10 min

o

Tensile modulus

MPa

1862

Flexural strength

MPa

36

Flexural modulus

MPa

1586

Mold shrinkage

%

0.6 to 0.8

Drying time

h

2

Drying temperature

o

C

79

HEALTH & SAFETY HMIS personal protection

No specific recommendations (dust mask, neoprene or synthetic rubber gloves, eye/face protection)

UN risk phrases, R

-

US safety phrases, S

26,28,36/37/39,45,57

UN/NA class

-

2735

ICAO/IATA class

-

II

Proper shipping name

Amines, liquid, corrosive, n.o.s. (alkyl(C12-C14)bis(hydroxyethyl)amine)

Flash point

o

Flash point method

-

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

22,34,50

193 COC 68

Armostat 400 PARAMETER

UNIT

VALUE

Animal testing, acute toxicity, Rat oral LD50

mg/kg

1500

First aid, eyes

Rinse immediately and as long as possible with plenty of water. Eyelids should be held away from the eyeball to ensure thorough rinsing. Always seek medical advice

First aid, skin

Remove all contaminated clothing immediately. Wash off with plenty of soap and water. Always seek medical advice. Launder clothes before reuse

First aid, inhalation

Seek medical advice after significant exposure

ECOLOGICAL PROPERTIES Biodegradation probability

Readily biodegradable

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.84 AKZO Nobel

USE & PERFORMANCE Manufacturer

-

Outstanding properties

Fast migration; direct dosing into extruder; dispersion aid for pigments; good thermal stability; low color

Recommended for polymers

PE, LDPE, PP, SAN, ABS, HIPS

Recommended dosage

PE, PP (0.1 to 0.3%), PS (2 to 4%), SAN (1 to 2%), ABS (1.5 to 3%), HIPS (1.5 to 2.5%)

Processing methods

Extrusion

Additive application method

Internal addition

Antistatics Databook / Copyrights 2014; ChemTec Publishing

69

Armostat 600 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Armostat 600

CAS #

-

Common name

Alkyl(C14-C18)bis(2-hydroxyethyl) amine

Common synonym

Hydrogenated tallowbis(2-hydroxyethyl) amine

EC number

-

291-276-3

Molecular mass

daltons

338 to 360

Chemical category

-

amine

Moisture content

wt%

0.5

90367-28-5

PHYSICAL PROPERTIES Color

-

yellowish

Color, Platinum-cobalt scale

-

300 max

Density at 20oC

kg/m3

960

Solubility in water at 25 C

g/l

practically insoluble

Izod impact notched

J/m

no break

Izod impact unnoched

J/m

no break

o

Tensile strength

MPa

28

Tensile elongation

%

6 to 9

Tensile modulus

MPa

2344

Flexural strength

MPa

41

Flexural modulus

MPa

1862

Mold shrinkage

%

0.4 to 0.6

Drying time

h

2

Drying temperature

o

C

79

HEALTH & SAFETY Food approval(s)

Indirect food contact and articles for carrying drinking water

Flash point

o

Flash point method

-

COC

Manufacturer

-

AKZO Nobel

Outstanding properties

Excellent thermal stability

Recommended for polymers

PE, LLDPE, PP, SAN and ABS

C

219

USE & PERFORMANCE

Recommended for products

Film, moldings

Recommended dosage

PE, LLDPE, PP (0.1 to 0.3%), ABS (1.5 to 3%)

Antistatics Databook / Copyrights 2014; ChemTec Publishing

70

Aromox C-12 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Aromox C-12

CAS #

-

Common name

Ethanol, 2,2'-iminobis-, N-coco alkyl derivs., N-oxides

Common synonym

Bis(2-hydroxyethyl)cocoalkylamine oxides

Mixture

-

yes

EC number

-

263-180-1

Chemical category

-

amine

Odor

-

alcohol-like

Color

colorless to light yellow

Color, Gardner scale

-

Boiling point

o

C

80

Melting point

o

C

-19

Pour point

o

C

-15

61791-47-7

PHYSICAL PROPERTIES

6

Specific gravity at 20 C

-

0.948

Vapor density

-

2.07

Vapor pressure at 20oC

kPa

2.66

o

Viscosity at 20 C

mPas

30

Solubility in water at 25oC

g/l

soluble

Solubility in solvents

methanol, acetone

Izod impact notched

J/m

80

Izod impact unnoched

J/m

187

Tensile strength

MPa

33

o

Tensile elongation

%

2 to 4

Tensile modulus

MPa

4482

Flexural strength

MPa

52

Flexural modulus

MPa

3310

Mold shrinkage

%

0.2 to 0.4

Drying time

h

2

Drying temperature

o

C

79

HEALTH & SAFETY NFPA classification

Health

3

Flammability

3

Reactivity

0

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71

Aromox C-12 PARAMETER

UNIT

VALUE

HMIS classification

Health

3

Flammability

3

Reactivity

0

HMIS personal protection

Face shield, full suit, vapor respirator, gloves, and boots

UN/NA class

-

1993

DOT class

-

group II, class 3

ICAO/IATA class

-

group II, class 3

TDG class

-

group II, class 3

Proper shipping name

Flammable liquids, n.o.s. (isopropyl alcohol)

Autoignition temperature

o

C

450

Flash point

o

C

22

Explosive LEL

wt%

2

Explosive UEL

wt%

12.7

Animal testing, acute toxicity, Rat oral LD50

mg/kg

4,650

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

12800

Animal testing, acute toxicity, Rat inhalation, LC50

ppm

16000

Skin irritation

Slightly irritating to the skin. Practically non-toxic in contact with skin

Eye irritation (human)

Severely irritating to the eyes

First aid, eyes

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately

First aid, skin

Wash with soap and water. Get medical attention if irritation develops. Cold water may be used

First aid, inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear

Carcinogenicity

IARC, NTP, OSHA, ACGIH: Not listed

ECOLOGICAL PROPERTIES Biodegradation probability

Readily biodegradable

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

Antistatics Databook / Copyrights 2014; ChemTec Publishing

1.1

72

Aromox C-12 PARAMETER

UNIT

VALUE

Manufacturer

-

AKZO Nobel

Davis scale

-

24.7

Concentration of active ingredients

wt%

49 to 53

USE & PERFORMANCE

Antistatics Databook / Copyrights 2014; ChemTec Publishing

73

Aromox DMC PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Aromox DMC

CAS #

-

Common name

Amines, coco alkyldimethyl, n-oxides

Common synonym

Dimethylcocoalkylamine oxides

Mixture

-

yes

EC number

-

263-016-9

Chemical category

-

amine

61788-90-7

PHYSICAL PROPERTIES Boiling point

o

C

80

Melting point

o

C

-36

Pour point

o

C

-32

Density at 20 C

kg/m

Vapor density

-

2

Vapor pressure at 20oC

kPa

2.9

o

3

890

Viscosity at 25 C

mPas

30

Solubility in water at 25oC

g/l

soluble

Solubility in solvents

methanol, acetone

Izod impact notched

J/m

64

Izod impact unnoched

J/m

160

o

Tensile strength

MPa

34

Tensile elongation

%

2 to 4

Tensile modulus

MPa

5171

Flexural strength

MPa

55

Flexural modulus

MPa

3999

Mold shrinkage

%

0.15 to 0.3

Drying time

h

2

Drying temperature

o

C

79

HEALTH & SAFETY NFPA classification

HMIS classification

HMIS personal protection

Health

3

Flammability

3

Reactivity

0

Health

3

Flammability

3

Reactivity

0

Face shield, full suit, vapor respirator, gloves, and boots

Antistatics Databook / Copyrights 2014; ChemTec Publishing

74

Aromox DMC PARAMETER

UNIT

VALUE

UN/NA class

-

1993

DOT class

-

group II, class 3

ICAO/IATA class

-

group II, class 3

TDG class

-

group II, class 3

Proper shipping name

Flammable liquids, n.o.s. (isopropyl alcohol)

Autoignition temperature

o

C

398

Flash point

o

C

21

Explosive LEL

wt%

2

Explosive UEL

wt%

12.7

Animal testing, acute toxicity, Rat oral LD50

mg/kg

5,500

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

520

Skin irritation

Slightly irritating to the skin. Practically non-toxic in contact with skin

Eye irritation (human)

Severely irritating to the eyes

First aid, eyes

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately

First aid, skin

Wash with soap and water. Get medical attention if irritation develops. Cold water may be used

First aid, inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear

Carcinogenicity

IARC, NTP, OSHA, ACGIH: Not listed

ECOLOGICAL PROPERTIES Biodegradation probability

Readily biodegradable

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

17.9

-

AKZO Nobel

USE & PERFORMANCE Manufacturer

Antistatics Databook / Copyrights 2014; ChemTec Publishing

75

Arquad 12-37W PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Arquad 12-37W

CAS #

-

Common name

Dodecyltrimethyl ammonium chloride

Common synonym

1-Dodecanaminium, N,N,N-trimethylchloride

112-00-5

IUPAC name

dodecyltrimethylamine chloride

Empirical formula

-

Formula

C15H34ClN

Cl CH3(CH2)10CH2N(CH3)3

EC number

-

203-927-0

Molecular mass

daltons

263.89

Chemical category

-

amine 2

PHYSICAL PROPERTIES Color, Gardner scale

-

Boiling point

o

C

100

Melting point

o

C

-3

Specific gravity at 25 C

-

0.969

pH

-

6.5 to 9

o

Surface tension at 25 C

mN/m

33

Solubility in water at 25oC

g/l

easily soluble in hot and cold water

Solubility in solvents

methanol acetone

Izod impact notched

J/m

53

Izod impact unnoched

J/m

534

o

Tensile strength

MPa

15

Tensile elongation

%

6 to 10

Tensile modulus

MPa

1517

Flexural strength

MPa

31

Flexural modulus

MPa

1379

Mold shrinkage

%

1.0 to 1.5

Drying time

h

2

Drying temperature

o

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

79

76

Arquad 12-37W PARAMETER

UNIT

VALUE

Health

3

Flammability

1

Reactivity

0

HEALTH & SAFETY NFPA classification

HMIS personal protection

Face shield, full suit, vapor respirator, gloves, and boots

DOT class

-

not regulated

ICAO/IATA class

-

not regulated

TDG class

-

not regulated

Flash point

o

Animal testing, acute toxicity, Rat oral LD50

mg/kg

684

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

1600

Skin irritation

Harmful in contact with skin. May cause sensitization by skin contact. Moderately irritating to the skin

Eye irritation (human)

Causes moderate eye irritation

First aid, eyes

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately

First aid, skin

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention

First aid, inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

C

100 min

ECOLOGICAL PROPERTIES Biodegradation probability

Readily biodegradable

Aquatic toxicity, Bluegill sunfish, 96-h LC50

mg/l

19.4

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.28

Partition coefficient, log Kow

-

1.22

Antistatics Databook / Copyrights 2014; ChemTec Publishing

77

Arquad 12-37W PARAMETER

UNIT

VALUE

USE & PERFORMANCE Manufacturer

AKZO Nobel United States

Davis scale

-

23

Concentration of active ingredients

wt%

35 to 39

Antistatics Databook / Copyrights 2014; ChemTec Publishing

78

Arquad 16-29 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Arquad 16-29

CAS #

-

Common name

Hexadecyltrimethyl ammonium chloride

Common synonym

1-Hexadecanaminium, N,N,N-trimethyl-, chloride

112-02-7

IUPAC name

hexadecyltrimethylamine chloride

Empirical formula

-

Formula

C19H42ClN

Cl CH3(CH2)14CH2N(CH3)3

EC number

-

203-928-6

Molecular mass

daltons

319.3

Chemical category

-

amine

PHYSICAL PROPERTIES Odor

-

faint

Color, Gardner scale

-

3

Boiling point

o

C

Melting point

o

C

Specific gravity at 25oC

-

0.961

Vapor pressure at 20oC

kPa

2.26

pH

-

6.5 to 9

mN/m

34

Surface tension at 25 C o

100 10

Izod impact notched

J/m

no break

Izod impact unnoched

J/m

no break

Tensile strength

MPa

21

Tensile elongation

%

10 min

Tensile modulus

MPa

1379

Flexural strength

MPa

31

Flexural modulus

MPa

1172

Mold shrinkage

%

1.2 to 1.7

Drying time

h

Drying temperature

o

C

2 79

HEALTH & SAFETY NFPA classification

Health

2

Flammability

1

Reactivity

0

Antistatics Databook / Copyrights 2014; ChemTec Publishing

79

Arquad 16-29 PARAMETER

UNIT

HMIS personal protection

Face shield, full suit, vapor respirator, gloves, and boots

DOT class

-

Proper shipping name

Flammable liquid, toxic, corrosive, n.o.s. (isopropanol, quaternary ammonium salts)

Flash point

o

Explosive LEL

wt%

2

Explosive UEL

wt%

12.7

Animal testing, acute toxicity, Rat oral LD50

mg/kg

1300 to 1700

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

4300

Skin irritation

Absorbed through skin

Eye irritation (human)

Causes moderate eye irritation

First aid, eyes

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately

First aid, skin

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention

First aid, inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

C

VALUE

not regulated

100

ECOLOGICAL PROPERTIES Biodegradation probability

Readily biodegradable

Partition coefficient, log Kow

-

3.18

USE & PERFORMANCE Manufacturer

AKZO Nobel United States

Davis scale

-

21

Concentration of active ingredients

wt%

27 to 30

Antistatics Databook / Copyrights 2014; ChemTec Publishing

80

Arquad C-33W PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Arquad C-33W

CAS #

-

Common name

Cocoalkyltrimethyl ammonium chloride

Common synonym

Coco alkyl trimethyl chloride

EC number

-

263-038-9

Chemical category

-

amine

Color, Gardner scale

-

4

Boiling point

o

C

100

Melting point

o

C

4

61789-18-2

PHYSICAL PROPERTIES

Specific gravity at 25oC

-

0.972

Vapor pressure at 20 C

kPa

1.87

pH

-

6 to 9

mN/m

31

Izod impact notched

J/m

64

Izod impact unnoched

J/m

427

o

Surface tension at 25 C o

Tensile strength

MPa

131

Tensile elongation

%

2 to 4

Tensile modulus

MPa

10342

Flexural strength

MPa

200

Flexural modulus

MPa

8274

Mold shrinkage

%

0.2 to 0.4

Drying time

h

Drying temperature

o

C

4 79

HEALTH & SAFETY NFPA classification

Health

2

Flammability

1

Reactivity

0

HMIS personal protection

Splash goggles, full suit, boots, gloves

DOT class

-

not regulated

ICAO/IATA class

-

not regulated

TDG class

-

not regulated

Flash point

o

C

100

Flash point method

-

PMCC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

684

Antistatics Databook / Copyrights 2014; ChemTec Publishing

81

Arquad C-33W PARAMETER

UNIT

VALUE

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

1600

First aid, eyes

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately

First aid, skin

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention

First aid, inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

ECOLOGICAL PROPERTIES Biodegradation probability

Readily biodegradable

Aquatic toxicity, Bluegill sunfish, 96-h LC50

mg/l

1.94

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.28

Partition coefficient, log Kow

-

2.35

USE & PERFORMANCE Manufacturer

AKZO Nobel United States

Davis scale

-

23

Concentration of active ingredients

wt%

32 to 35

Antistatics Databook / Copyrights 2014; ChemTec Publishing

82

Arquad DMHTB-75 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Arquad DMHTB-75

CAS #

-

Common name

Benzyldimethyl(hydrogenated tallowalkyl) ammonium chloride

Common synonym

Dimethyl benzyl hydrogenated tallow ammonium chloride

EC number

-

263-081-3

Chemical category

-

amine

Color

-

white

Color, Gardner scale

-

4

Boiling point

o

C

80

Melting point

o

C

35

Pour point

o

C

44

61789-72-8

PHYSICAL PROPERTIES

Vapor pressure at 20 C

kPa

5.87

pH

-

7 to 9

Izod impact notched

J/m

53

Izod impact unnoched

J/m

374

Tensile strength

MPa

197

o

Tensile elongation

%

1 to 2

Tensile modulus

MPa

8274

Flexural strength

MPa

131

Flexural modulus

MPa

6895

Mold shrinkage

%

0.3 to 0.5

Drying time

h

4

Drying temperature

o

C

79

HEALTH & SAFETY NFPA classification

Health

3

Flammability

3

Reactivity

0

HMIS personal protection

Splash goggles, full suit, vapor respirator, boots, gloves

UN/NA class

-

2924

DOT class

-

class 3 group III

ICAO/IATA class

-

class 3 group III

TDG class

-

class 3 group III

Autoignition temperature

o

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

450 83

Arquad DMHTB-75 PARAMETER

UNIT

VALUE

Flash point

o

C

23

Explosive LEL

wt%

2

Explosive UEL

wt%

12.7

Animal testing, acute toxicity, Rat oral LD50

mg/kg

4710

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

12800

Skin irritation

Practically non-toxic in contact with skin

Eye irritation (human)

Corrosive to the eyes

First aid, eyes

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately

First aid, skin

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention

First aid, inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

ECOLOGICAL PROPERTIES Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.019

USE & PERFORMANCE Manufacturer

AKZO Nobel United States

Davis scale

-

18

Concentration of active ingredients

wt%

75 to 80

Antistatics Databook / Copyrights 2014; ChemTec Publishing

84

Arquad HTL8-MS PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Arquad HTL8-MS

CAS #

-

Common name

Hydrogenated tallowalkyl(2-ethylhexyl) dimethyl ammonium methylsufate

Chemical category

-

amine

Color, Gardner scale

-

5

Boiling point

o

C

100

Melting point

o

C

-4

Density at 40oC

kg/m3

955

kPa

0.44

308074-31-9

PHYSICAL PROPERTIES

Vapor pressure at 20 C o

pH

-

6 to 8

Izod impact notched

J/m

53

Izod impact unnoched

J/m

427

Tensile strength

MPa

172

Tensile elongation

%

2 to 4

Tensile modulus

MPa

10342

Flexural strength

MPa

241

Flexural modulus

MPa

8964

Mold shrinkage

%

0.15 to 0.35

Drying time

h

4

Drying temperature

o

C

79

HEALTH & SAFETY NFPA classification

Health

2

Flammability

1

Reactivity

0

HMIS personal protection

Splash goggles, full suit, boots, gloves

DOT class

-

not regulated

ICAO/IATA class

-

not regulated

TDG class

-

not regulated

Flash point

o

Animal testing, acute toxicity, Rat oral LD50

mg/kg

1410

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

2000 min

Skin irritation

Moderately irritating to the skin. Practically non-toxic in contact with skin

Eye irritation (human)

Severely irritating to the eyes

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

100

85

Arquad HTL8-MS PARAMETER

UNIT

VALUE

First aid, eyes

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately

First aid, skin

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention

First aid, inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

USE & PERFORMANCE Manufacturer

AKZO Nobel United States

Davis scale

-

17.5

Concentration of active ingredients

wt%

81.5 to 84.5

Antistatics Databook / Copyrights 2014; ChemTec Publishing

86

Arquad S-50 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Arquad S-50

CAS #

-

Common name

Soyaalkyltrimethyl ammonium chloride

Common synonym

(Soya alkyl) trimethyl ammonium chloride

61790-41-8

EC number

-

263-134-0

Chemical category

-

amine

PHYSICAL PROPERTIES Melting point

o

Specific gravity at 25oC

-

C

0.869

-13

Vapor pressure at 20oC

kPa

3.33

pH

-

6 to 9

Viscosity SUS at 37.8oC

s

982

Surface tension at 25oC

mN/m

34

Izod impact notched

J/m

80

Izod impact unnoched

J/m

534

Tensile strength

MPa

165

Tensile elongation

%

2 to 4

Tensile modulus

MPa

13790

Flexural strength

MPa

241

Flexural modulus

MPa

11032

Mold shrinkage

%

0.1 to 0.2

Drying time

h

Drying temperature

o

C

4 79

HEALTH & SAFETY NFPA classification

Health

3

Flammability

3

Reactivity

0

HMIS personal protection

Splash goggles, full suit, vapor respirator, boots, gloves

UN/NA class

-

1992

DOT class

-

class 3 group II

ICAO/IATA class

-

class 3 group II

TDG class

-

class 3 group II

Proper shipping name

Flammable liquid, toxic, n.o.s. (isopropanol, quaternary ammonium salts)

Autoignition temperature

o

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

450 87

Arquad S-50 PARAMETER

UNIT

VALUE

Flash point

o

C

18

Explosive LEL

wt%

2

Explosive UEL

wt%

12.7

Animal testing, acute toxicity, Rat oral LD50

mg/kg

464

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

2000 min

Skin irritation

Severely irritating to the skin. Practically non-toxic in contact with skin.

Eye irritation (human)

Corrosive to the eyes.

First aid, eyes

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately

First aid, skin

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention

First aid, inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

ECOLOGICAL PROPERTIES Aquatic toxicity, Rainbow trout, 96-h LC50

mg/l

0.3

USE & PERFORMANCE Manufacturer

AKZO Nobel United States

Davis scale

-

21

Concentration of active ingredients

wt%

49 to 52

Antistatics Databook / Copyrights 2014; ChemTec Publishing

88

Arquad T-27W PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Arquad T-27W

CAS #

-

Common name

Tallowalkyltrimethyl ammonium chloride

EC number

-

232-447-4

Chemical category

-

amine

Color, Gardner scale

-

3

Melting point

o

C

Pour point

o

C

Specific gravity at 25oC

-

0.974

Density at 40oC

kg/m3

955

Vapor pressure at 20 C

kPa

2.27

pH

-

6 to 9

s

45

8030-78-2

PHYSICAL PROPERTIES

o

Viscosity SUS at 37.8 C o

18 18

Surface tension at 25 C

mN/m

34

Izod impact notched

J/m

107

Izod impact unnoched

J/m

no break

Tensile strength

MPa

52

Tensile elongation

%

10 min

o

Tensile modulus

MPa

2758

Flexural strength

MPa

90

Flexural modulus

MPa

2758

Mold shrinkage

%

1.2 to 1.6

Drying time

h

2

Drying temperature

o

C

82

HEALTH & SAFETY NFPA classification

Health

3

Flammability

1

Reactivity

0

HMIS personal protection

Splash goggles, full suit, boots, gloves

DOT class

-

not regulated

ICAO/IATA class

-

not regulated

TDG class

-

not regulated

Proper shipping name

Flammable liquid, toxic, n.o.s. (isopropanol, quaternary ammonium salts)

Flash point

o

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

100 89

Arquad T-27W PARAMETER

UNIT

VALUE

Animal testing, acute toxicity, Rat oral LD50

mg/kg

1260

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

2000 min

Skin irritation

Severely irritating to the skin. Practically non-toxic in contact with skin

Eye irritation (human)

Corrosive to the eyes

First aid, eyes

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately

First aid, skin

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention

First aid, inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

Mutagenicity

Non-mutagenic for bacteria and/or yeast

ECOLOGICAL PROPERTIES Biodegradation probability

Inherently biodegradable

Aquatic toxicity, Bluegill sunfish, 96-h LC50

mg/l

2.1

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.35

Aquatic toxicity, Rainbow trout, 96-h LC50

mg/l

0.3

USE & PERFORMANCE Manufacturer

AKZO Nobel United States

Davis scale

-

21

Concentration of active ingredients

wt%

26 to 29

Antistatics Databook / Copyrights 2014; ChemTec Publishing

90

Atmer 163 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Atmer 163

CAS #

-

Common name

Ethoxylated amine

Common synonym

N,N-bis(2-hydroxyethyl)alkylamine

Mixture

-

yes

Chemical category

-

amine

State

-

liquid

Color

clear, white to yellow

71786-60-2

PHYSICAL PROPERTIES

Melting point

o

C

-2

Specific gravity at 25 C

-

Density at 25 C

kg/m

Surface resistivity

Ohm/sq

5.0E13 (0.2%)

pH

-

9 to 10

Izod impact notched

J/m

133

Izod impact unnoched

J/m

641

o

o

0.91 3

910

Tensile strength

MPa

110

Tensile elongation

%

3 to 5

Tensile modulus

MPa

8274

Flexural strength

MPa

165

Flexural modulus

MPa

6206

Mold shrinkage

%

0.2 to 0.4

Drying time

h

Drying temperature

o

C

4 79

HEALTH & SAFETY NFPA classification

Health

3

Flammability

1

Reactivity

0

Health

3

Flammability

1

Reactivity

0

UN risk phrases, R

-

22,34,50/53

US safety phrases, S

-

26,37/39,57,61

UN/NA class

-

2735

DOT class

-

class 8 group II

ICAO/IATA class

-

class 8 group II

HMIS classification

Antistatics Databook / Copyrights 2014; ChemTec Publishing

91

Atmer 163 PARAMETER

UNIT

VALUE class 8 group II

TDG class

-

Autoignition temperature

o

C

290

Flash point

o

C

174

Flash point method

-

PMCC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

500 to 5000

Skin irritation

This material will induce chemical burns following contact with human skin. Systemically toxic concentrations of this product will probably not be absorbed through human skin

Eye irritation (human)

This material can induce chemical burns on contact with human eyes

First aid, eyes

Immediately flush with plenty of water for at least 15 minutes. If redness, itching, or a burning sensation develops, have eyes examined and treated by medical personnel

First aid, skin

Wash material off of the skin with plenty of soap and water. If redness, itching, or a burning sensation develops, get medical attention

First aid, inhalation

Remove victim to fresh air. If a cough or other respiratory symptoms develop, consult medical personnel

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

ECOLOGICAL PROPERTIES Partition coefficient, log Kow

-

5.47

Manufacturer

-

Croda

Concentration of active ingredients

wt%

30-50

Outstanding properties

Synergistic mixtures with Atmer 129; in injection molding improves surface finish

Recommended for polymers

L/LDPE, HDPE, PP, crystal PS, SAN, HIPS, ABS, EVA, PVC, rubber, TPE

Recommended for products

caps, closures, film

Recommended dosage

L/LDPE (0.05 to 0.1%), HDPE (0.15 to 0.5%), PP (0.15 to 0.3%, with Atmer 129 0.2 to 0.6%), crystal PS (1 to 1.5%), SAN (1 to 1.5%), HIPS (1 to 1.5%), ABS (1 to 2%)

Processing methods

Film, injection molding, sheet extrusion, and polypropylene polymerization

USE & PERFORMANCE

Antistatics Databook / Copyrights 2014; ChemTec Publishing

92

Atmer 7003 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Atmer 7003

Common name

Ethoxylated amine

Mixture

-

yes

Chemical category

-

amine

PHYSICAL PROPERTIES State

-

pellets

Color

-

white to pale yellow

Melting point

o

C

150 min

Surface resistivity

Ohm/sq

5.0E13 (1% in PP)

Izod impact notched

J/m

53

Izod impact unnoched

J/m

534

Tensile strength

MPa

76

Tensile elongation

%

3 to 5

Tensile modulus

MPa

5861

Flexural strength

MPa

124

Flexural modulus

MPa

5516

Mold shrinkage

%

0.2 to 0.4

Drying time

h

4

Drying temperature

o

C

121

HEALTH & SAFETY HMIS personal protection

Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure limit is likely

UN risk phrases, R

-

22,34,50/53

US safety phrases, S

-

26,37/39,57,61

UN/NA class

-

3077

DOT class

-

class 9 group III

ICAO/IATA class

-

class 9 group III

TDG class

-

class 9 group III

Proper shipping name

Environmentally hazardous substance, solid, n.o.s. (contains alkylamine ethoxylate)

Flash point

o

Skin irritation

Irritating to skin. Molten polymer will adhere to the skin causing deep thermal burns

Eye irritation (human)

Irritating to eyes. May cause physical abrasion in contact with eyes

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

100 min

93

Atmer 7003 PARAMETER

UNIT

VALUE

First aid, eyes

Irrigate with eyewash solution or clean water, holding the eyelids apart, for at least 10 minutes. Obtain medical attention

First aid, skin

Remove contaminated clothing. Wash skin with soap and water. If symptoms develop, obtain medical attention

First aid, inhalation

Remove patient from exposure. Obtain medical attention if ill effects occur

USE & PERFORMANCE Manufacturer

-

Croda

Concentration of active ingredients

wt%

30 to 50

Recommended for polymers

HDPE, LDPE, LLDPE, PP, clear styrenics (internal); ABS, EVA, HDPE, ionomers, TPE, LDPE, LLDPE, PC, PP, PVC, rubber, polyesters, styrenics (external)

Recommended for products

caps, closures, film, vinyl plastisols, foamed polymers

Features & benefits

Not suitable for fibers and films thinner than 30 micrometers

Processing methods

Injection molding and sheet extrusion: 0.1 to 0.3%

Antistatics Databook / Copyrights 2014; ChemTec Publishing

94

Atmer 7325 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Atmer 7325

Common name

Alkylamine ethoxylate (one of the components)

Mixture

-

yes

EC number

-

276-014-8

Chemical category

-

amine

Color

-

off-white

Melting point

o

C

150 min

Solubility in water at 25oC

g/l

insoluble

Izod impact notched

J/m

53

Izod impact unnoched

J/m

267

Tensile strength

MPa

21

Tensile elongation

%

3 to 6

PHYSICAL PROPERTIES

Tensile modulus

MPa

2068

Flexural strength

MPa

38

Flexural modulus

MPa

2413

Mold shrinkage

%

0.4 to 0.6

Drying time

h

2

Drying temperature

o

C

82

HEALTH & SAFETY HMIS personal protection

Neoprene gloves, respiratory protection, safety glasses

UN risk phrases, R

-

22,34,50/53

US safety phrases, S

-

57,61

UN/NA class

-

3077

DOT class

-

class 9 group III

ICAO/IATA class

-

class 9 group III

TDG class

-

class 9 group III

Proper shipping name

Environmentally hazardous substance, solid, n.o.s. (contains alkylamine ethoxylate)

Flash point

o

Skin irritation

Unlikely to cause skin irritation

Eye irritation (human)

May cause physical abrasion in contact with eyes

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

150 min

95

Atmer 7325 PARAMETER

UNIT

VALUE

First aid, eyes

Irrigate with eyewash solution or clean water, holding the eyelids apart, for at least 10 minutes. Obtain medical attention

First aid, skin

Remove contaminated clothing. Wash skin with soap and water. If symptoms develop, obtain medical attention

First aid, inhalation

Remove patient from exposure. Obtain medical attention if ill effects occur

USE & PERFORMANCE Manufacturer

-

Outstanding properties

Antistatic concentrate containing highly effective synergistic combination of antistatic agents

Recommended for polymers

PE

Recommended for products

Caps, film, sheet

Features & benefits

Not suitable for fibers

Processing methods

Film thicker than 30 micrometers (0.5 to 1%), injection molding (0.5 to 1.5%), blow molding, sheet extrusion (0.5 to 1.5%)

Antistatics Databook / Copyrights 2014; ChemTec Publishing

Croda

96

Carsoquat 450I PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Carsoquat 450I

CAS #

-

Common name

Cetrimonium chloride (50%), propanol2-ol (35%), water (15%)

Common synonym

Cetyl trimethyl ammonium chloride

Formula

112-02-7

Cl CH3(CH2)14CH2N(CH3)3

Mixture

-

yes

Chemical category

-

amine

Moisture content

wt%

15

PHYSICAL PROPERTIES State

-

liquid

Color

-

light amber

Color, Gardner scale

-

3 max

Boiling point

o

Density at 20 C o

C

kg/m

80 3

870

pH

-

3.5 to 9

Solubility in water at 25oC

g/l

dispersible

Solubility in solvents

lower alcohols, ketones, glycols

HEALTH & SAFETY HMIS classification

Health

3

Flammability

3

Reactivity

0

DOT class

-

3 UN2924

Autoignition temperature

o

C

Flash point

o

C

Flash point method

-

Pensky-Martens

Explosive LEL

wt%

2

Explosive UEL

wt%

12

Animal testing, acute toxicity, Rat oral LD50

mg/kg

1290

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

4171

425 21

ECOLOGICAL PROPERTIES Biodegradation probability

100%

Aquatic toxicity, Bluegill sunfish, 96-h LC50

mg/l

Antistatics Databook / Copyrights 2014; ChemTec Publishing

0.1 97

Carsoquat 450I PARAMETER

UNIT

VALUE

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.01

Partition coefficient, log Kow

-

3.18

USE & PERFORMANCE Manufacturer

-

Lonza

Concentration of active ingredients

wt%

50

Recommended for products

Hair conditioners, cream rinses

Additive application method

Incorporation

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98

Carsoquat SQD-85 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Carsoquat SQD-85

CAS #

-

Common name

Quaternary ammonium chloride

122-19-0

Formula

Cl CH3(CH2)17NCH2

Molecular mass

daltons

423.6

Chemical category

-

amine

PHYSICAL PROPERTIES State

-

liquid

Odor

-

soapy

Color

-

white to off-white

pH

-

3.5 to 6.5

Solubility in water at 25 C

g/l

dispersible

Solubility in solvents

lower alcohols, ketones, glycols

o

HEALTH & SAFETY Flash point

o

C

Flash point method

-

65.5 Setaflash

ECOLOGICAL PROPERTIES Biodegradation probability

100%

Partition coefficient, log Kow

-

5.87

Manufacturer

-

Lonza

Concentration of active ingredients

wt%

85

USE & PERFORMANCE

Recommended for products

Hair conditioners, cream rinses

Additive application method

Incorporation

Antistatics Databook / Copyrights 2014; ChemTec Publishing

99

Carstat 10 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Carstat 10

Common name

Quaternary ammonium salt of fatty acid amide

Chemical category

-

amine

State

-

liquid

Odor

-

isopropanol

PHYSICAL PROPERTIES

Color

-

clear, pale yellow

Density at 20 C

kg/m

pH

-

4.0 to 6.0

mPas

20 to 40

Solubility in water at 25 C

g/l

miscible

Solubility in solvents

miscible with acetone, methanol, ethanol, ethylene glycol, and tetrahydrofuran

o

Viscosity at 20 C o

o

3

900 to 960

HEALTH & SAFETY NFPA classification

Health

0

Flammability

1

Reactivity

0

UN risk phrases, R

-

10

US safety phrases, S

-

7,9,13,16

UN/NA class

-

1219

DOT class

-

group III, class 3

ICAO/IATA class

-

group III, class 3

TDG class

-

group III, class 3

Proper shipping name

Quaternary ammonium salt, isopropyl alcohol - water solution

Autoignition temperature

o

C

456

Flash point

o

C

22

Explosive LEL

wt%

2.5

Explosive UEL

wt%

5.2

Animal testing, acute toxicity, Rat oral LD50

mg/kg

1800 min

Skin irritation

May cause skin irritation

Eye irritation (human)

May cause eye damage on prolonged contact

First aid, eyes

Immediately irrigate with plenty of water for 15 minutes. Obtain medical attention

First aid, skin

Wash affected areas of skin with plenty of soap and water

Antistatics Databook / Copyrights 2014; ChemTec Publishing

100

Carstat 10 PARAMETER

UNIT

VALUE

Manufacturer

-

Carmel Resins Ltd.

Concentration of active ingredients

wt%

50

Recommended for polymers

PS (especially expanded)

Recommended for products

Plastic films, textiles, paper, electronic parts

USE & PERFORMANCE

Recommended dosage

wt%

Additive application method

Spraying, dipping, brushing, or wiping using solution containing 0.2 to 1% solids

Antistatics Databook / Copyrights 2014; ChemTec Publishing

0.08

101

Catafor F PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Catafor F

CAS #

-

Common name

Ethylsulfate ammonium quaternary surfactant

Mixture

-

yes

Chemical category

-

amine

Moisture content

wt%

0.5

Density at 20oC

kg/m3

998

pH

-

6 to 8

68308-64-5

PHYSICAL PROPERTIES

HEALTH & SAFETY Flash point

o

C

100 min

USE & PERFORMANCE Manufacturer

Rhodia China (Solvay)

Concentration of active ingredients

wt%

Outstanding properties

High efficiency, excellent polymer compatibility

Recommended for polymers

High density PU

Recommended for products

Shoe soles

Antistatics Databook / Copyrights 2014; ChemTec Publishing

80

102

Chemstat 106G-90 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Chemstat 106G-90

CAS #

-

Common name

1-Octanaminium, N,N-bis(2hydroxyethyl)-N-methyl-, salt with 4-methylbenzenesulfonic acid (1:1)

Common synonym

Bis(2-hydroxyethyl)methyloctylammonium toluene-p-sulfonate

Empirical formula

-

58767-50-3

C20H37NO5S

Formula

O O S O CH3(CH2)7N(CH2CH2OH)2

EC number

-

261-430-4

Molecular mass

daltons

403.57

Chemical category

-

amine

Moisture content

wt%

12

-

liquid

PHYSICAL PROPERTIES State Odor

characteristic of quaternary compounds

Color

-

Boiling point

o

C

yellow to amber 100

Specific gravity at 20 C

-

1.1

Surface resistivity

Ohm/sq

1E+10

Static decay time

s

0.07

pH

-

5 to 8

Viscosity at 25 C

mPas

16

Volatility

wt%

10

Health

3

o

o

HEALTH & SAFETY NFPA classification

Flammability

1

Reactivity

0

HMIS personal protection

Safety glasses with side shields, NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge, body covering-clothing, neoprene or butyl rubber gloves

UN risk phrases, R

-

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34 103

Chemstat 106G-90 PARAMETER

UNIT

VALUE

US safety phrases, S

-

24/25,36/37/39

UN/NA class

-

1760

DOT class

-

group III, class 8

ICAO/IATA class

-

group III, class 8

TDG class

-

group III, class 8

Proper shipping name

Corrosive Liquids, n.o.s., 8, UN 1760, PG III, (contains quaternary ammonium salts)

Flash point

o

Flash point method

-

COC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

1410

Skin irritation

Can cause severe irritation or burns with redness, swelling, or blisters

Eye irritation (human)

Will cause eye burns and permanent tissue damage

Ingestion

May cause severe damage to mouth, throat, and stomach

C

93

Chronic effects First aid, eyes

Immediately flush eyes with water for at least 15 minutes. Do not let victim rub eyes. Seek medical attention immediately

First aid, skin

Immediately wash skin with plenty of soap and water while removing contaminated clothing and shoes. Get medical attention. Contaminated clothing should be discarded in a manner which limits further exposure

First aid, inhalation

Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

ECOLOGICAL PROPERTIES Partition coefficient, log Kow

-

1.41

USE & PERFORMANCE Manufacturer

-

PCC Chemax

Concentration of active ingredients

wt%

88

Outstanding properties

Easy handling, efficient

Recommended for polymers

PS, PC, and other thermoplastics

Antistatics Databook / Copyrights 2014; ChemTec Publishing

104

Chemstat 106G-90 PARAMETER

UNIT

Recommended dosage

PS (2%), PC (1.6%), PA (0.8 to 1.3%), PETG (2%)

Processing methods

Extrusion, injection molding, blow molding

Additive application method

Internal addition to polymer (but can be used as external as well)

Antistatics Databook / Copyrights 2014; ChemTec Publishing

VALUE

105

Chemstat 122 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Chemstat 122

CAS #

-

Common name

Ethanol, 2,2’-iminobis-, N-coco alkyl derivatives

EC number

-

263-163-9

Chemical category

-

amine

Moisture content

wt%

0.5

-

liquid

61791-31-9

PHYSICAL PROPERTIES State Odor

amine

Color

water white to yellow

Boiling point

o

Specific gravity at 20oC

-

0.88

Surface resistivity

Ohm/sq

1.0E+09 to 1.0E+11

Static decay time

s

0.01 to 0.5

-

9 to 11

pH

C

217

Solubility in water at 25 C

g/l

insoluble

Volatility

wt%

1

Health

3

Flammability

1

Reactivity

0

o

HEALTH & SAFETY NFPA classification

HMIS personal protection

Safety glasses with side shields, NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge, body covering-clothing, neoprene or butyl rubber gloves

UN risk phrases, R

-

34

US safety phrases, S

-

26,28,36/37/39

UN/NA class

-

2735

DOT class

-

group III, class 8

ICAO/IATA class

-

group III, class 8

TDG class

-

group III, class 8

Proper shipping name

Amines, liquid, corrosive, n.o.s., 8 UN 2735, PG III (contains ethoxylated coco amines)

Autoignition temperature

o

C

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204.4 106

Chemstat 122 PARAMETER

UNIT

Flash point

o

Flash point method

-

Setaflash

Animal testing, acute toxicity, Rat oral LD50

mg/kg

1300

Skin irritation

Causes skin burns

Eye irritation (human)

Causes eye burns

Ingestion

May cause severe damage to mouth, throat and stomach

First aid, eyes

Immediately flush eyes with water for at least 15 minutes. Do not let victim rub eyes. Seek medical attention immediately

First aid, skin

Immediately wash skin with plenty of soap and water while removing contaminated clothing and shoes. Get medical attention. Contaminated clothing should be discarded in a manner which limits further exposure

First aid, inhalation

Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

C

VALUE 93

USE & PERFORMANCE Manufacturer

-

Outstanding properties

Easy handling, efficient, FDA approved, improves pigment dispersibility

Recommended for polymers

PE, PP, ABS

Recommended dosage

PE (0.1 to 0.4%), PP (0.1 to 0.8%), ABS (1.o to 4.0%)

Processing methods

Extrusion, injection molding, blow molding

Additive application method

Internal

Antistatics Databook / Copyrights 2014; ChemTec Publishing

PCC Chemax

107

Chemstat 122-60DC PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Chemstat 122-60DC

CAS #

-

Common name

Amines, C8-10 and C18-unsaturated, alkyl, ethoxylated

Mixture

-

yes

Chemical category

-

amines

-

solid

68439-72-5

PHYSICAL PROPERTIES State Odor

-

mild amine

Color

-

white to ivory

Bulk density

kg/m3

310

Solubility in water at 25 C

g/l

insoluble

Volatility

wt%

1

Health

3

Flammability

1

Reactivity

0

o

HEALTH & SAFETY NFPA classification

HMIS personal protection

Safety glasses with side shields, NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge, body covering-clothing, neoprene or butyl rubber gloves.

Food approval(s)

In polyolefin food contact films as cited in 21CFR 178.3130. Use levels are not to exceed 0.1% by weight

UN risk phrases, R

-

34

US safety phrases, S

-

26,28,36/38/39

UN/NA class

-

3259

DOT class

-

group III, class 8

ICAO/IATA class

-

group III, class 8

TDG class

-

group III, class 8

Proper shipping name

Amines, solid, corrosive, n.o.s., 8, UN 3259, PG III, (contains ethoxylated coco amine)

Flash point

o

C

93

Flash point method

-

COC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

1300

Skin irritation

Causes skin burns.

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108

Chemstat 122-60DC PARAMETER

UNIT

VALUE

Eye irritation (human)

Causes eye burns.

Ingestion

May cause severe damage to mouth, throat and stomach.

Chronic effects First aid, eyes

Immediately flush eyes with water for at least 15 minutes. Do not let victim rub eyes. Seek medical attention immediately.

First aid, skin

Immediately wash skin with plenty of soap and water while removing contaminated clothing and shoes. Get medical attention. Contaminated clothing should be discarded in a manner which limits further exposure.

First aid, inhalation

Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

ECOLOGICAL PROPERTIES Partition coefficient, log Kow

-

2.52

Manufacturer

-

PCC Chemax

Concentration of active ingredients

wt%

60

Outstanding properties

Easy to handle powder version of Chemstat 122

Recommended for polymers

PE, PP, ABS

Recommended for products

Film, moldings

Processing methods

Extrusion, injection, and blow-molding

Additive application method

Internal

USE & PERFORMANCE

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109

Chemstat 182 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Chemstat 182

CAS #

-

Common name

Ethanol, 2,2'-iminobis-, N-tallow alkyl derivatives

Common synonym

Bis(2-hydroxyethyl)tallow amine

61791-44-4

Chemical category

-

amine

Moisture content

wt%

0.5

-

liquid

PHYSICAL PROPERTIES State Odor

amine

Color

white to light yellow C

218

Boiling point

o

Specific gravity at 20oC

-

0.915

Volume resistivity

Ohm-cm

1.0E+09 (0.1% in LDPE) 1.0E+11 (0.4% in HDPE)

-

9 to 11

g/l

dispersible

Health

3

pH Solubility in water at 25 C o

HEALTH & SAFETY NFPA classification

Flammability

1

Reactivity

0

HMIS personal protection

Safety glasses with side shields, NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge, body covering-clothing, neoprene or butyl rubber gloves

UN risk phrases, R

-

34

US safety phrases, S

-

26,28,36/38/39

UN/NA class

-

2735

DOT class

-

group III, class 8

ICAO/IATA class

-

group III, class 8

TDG class

-

group III, class 8

Proper shipping name

Amines, liquid, corrosive, n.o.s., 8, UN 2735, PG III, (contains ethoxylated tallow amines)

Flash point

o

Flash point method

-

C

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93 COC 110

Chemstat 182 PARAMETER

UNIT

VALUE

Animal testing, acute toxicity, Rat oral LD50

mg/kg

600 to 1300

Skin irritation

Can cause severe irritation or burns with redness, swelling, or blisters

Eye irritation (human)

Will cause eye burns and permanent tissue damage

Ingestion

May cause severe damage to mouth, throat, and stomach

First aid, eyes

Immediately flush eyes with water for at least 15 minutes. Do not let victim rub eyes. Seek medical attention immediately

First aid, skin

Immediately wash skin with plenty of soap and water while removing contaminated clothing and shoes. Get medical attention. Contaminated clothing should be discarded in a manner which limits further exposure

First aid, inhalation

Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

USE & PERFORMANCE Manufacturer

-

PCC Chemax 100

Concentration of active ingredients

wt%

Outstanding properties

Easy handling, efficient, FDA approved, improves pigment dispersibility

Recommended for polymers

PE

Recommended dosage

LDPE (0.1%), HDPE (0.4%)

Processing methods

Extrusion, injection molding, blow molding

Additive application method

Internal

Antistatics Databook / Copyrights 2014; ChemTec Publishing

111

Chemstat 1913-50 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Chemstat 1913-50

CAS #

-

Common name

1-Propanaminium, N-(2-hydroxyethyl)N,N-dimethyl-3-[(1-oxooctadecyl) amino]-, nitrate (salt)

Empirical formula

-

2764-13-8

C25H53N3O5

Formula

O O N O

O CH3(CH2)16CN(CH2)3NCH2CH2OH

Mixture

-

yes

EC number

-

220-432-5

Molecular mass

daltons

475.7

Chemical category

-

amine

Moisture content

wt%

50

-

liquid

PHYSICAL PROPERTIES State Odor

alcohol

Color

clear

Color, Gardner scale

-

Boiling point

o

Specific gravity at 20oC

-

0.95

Vapor density

-

2

C

5 max 86.1

pH

-

4.0 to 5.5

Solubility in water at 25oC

g/l

soluble

Health

2

Flammability

3

Reactivity

0

HEALTH & SAFETY NFPA classification

HMIS personal protection

Safety glasses with side shields, NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge, body covering-clothing, neoprene or butyl rubber gloves

UN risk phrases, R

-

10,36/37/38

US safety phrases, S

-

26,43

UN/NA class

-

1993

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Chemstat 1913-50 PARAMETER

UNIT

VALUE

DOT class

-

group II, class 3

ICAO/IATA class

-

group II, class 3

TDG class

-

group II, class 3

Proper shipping name

Flammable liquids, n.o.s., 3, UN 1993, PG II, (contains isopropanol).

Flash point

o

Flash point method

-

PMCC

Explosive LEL

wt%

2.5

Explosive UEL

wt%

12

Skin irritation

Contact causes skin irritation; repeated or prolonged contact with IPA may result in defatting, cracking, or dermatitis. IPA may be absorbed by the skin resulting in headache, nausea, dizziness, or coma

Eye irritation (human)

Contact causes eye irritation; high concentrations of IPA vapors may cause eye irritation

Ingestion

May cause severe damage to mouth, throat, and stomach

C

12.2

Chronic effects First aid, eyes

Immediately flush eyes with water for at least 15 minutes. Do not let victim rub eyes. Seek medical attention immediately

First aid, skin

Immediately wash skin with plenty of soap and water while removing contaminated clothing and shoes. Get medical attention. Contaminated clothing should be discarded in a manner which limits further exposure

First aid, inhalation

Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

ECOLOGICAL PROPERTIES Partition coefficient, log Kow

-

3.41

Manufacturer

-

PCC Chemax

Recommended for polymers

Wide variety of substrates

Recommended dosage

0.25 to 0.5 (3% in EPS)

USE & PERFORMANCE

Antistatics Databook / Copyrights 2014; ChemTec Publishing

113

Chemstat 1913-50 PARAMETER

UNIT

VALUE

Features & benefits Processing methods

Spraying, dipping, brushing, or wiping using solution containing 0.2 to 0.5% solids

Additive application method

External

Antistatics Databook / Copyrights 2014; ChemTec Publishing

114

Chemstat 192T PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Chemstat 192T

CAS #

-

Common name

Ethanol, 2,2'-iminobis-, N-(hydrogenated tallow alkyl) derivatives

EC number

-

291-276-3

Chemical category

-

amine

Moisture content

wt%

1

90367-28-5

PHYSICAL PROPERTIES Color

slightly yellowish

Melting point

o

Specific gravity at 20 C o

Solubility in water at 25 C o

C

40

-

0.96

g/l

insoluble

Health

3

HEALTH & SAFETY NFPA classification

Flammability

1

Reactivity

0

HMIS personal protection

Safety glasses with side shields, NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge, body covering-clothing, neoprene or butyl rubber gloves

UN risk phrases, R

-

38,41,50

US safety phrases, S

-

26,28,37/39,57

UN/NA class

-

3077

DOT class

-

group III, class 9

ICAO/IATA class

-

group III, class 9

TDG class

-

group III, class 9

Proper shipping name

Environmentally hazardous substances, solid, n.o.s., 9, UN 3077, PG III, (contains ethoxylated hydrogenated tallow amines)

Flash point

o

C

219

Flash point method

-

COC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

2000

Skin irritation

Contact causes severe skin irritation. Contact with product at elevated temperatures can result in thermal burns

Antistatics Databook / Copyrights 2014; ChemTec Publishing

115

Chemstat 192T PARAMETER

UNIT

VALUE

Eye irritation (human)

Causes eye burns. Contact with product at elevated temperatures can result in thermal burns

Ingestion

May cause severe damage to mouth, throat and stomach

First aid, eyes

Immediately flush eyes with water for at least 15 minutes. Do not let victim rub eyes. Seek medical attention immediately

First aid, skin

Immediately wash skin with plenty of soap and water while removing contaminated clothing and shoes. Get medical attention. Contaminated clothing should be discarded in a manner which limits further exposure

First aid, inhalation

Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

USE & PERFORMANCE Manufacturer

-

PCC Chemax

Concentration of active ingredients

wt%

100

Recommended for polymers

Polyolefins

Processing methods

Extrusion, injection, and blow-molding

Additive application method

Internal

Antistatics Databook / Copyrights 2014; ChemTec Publishing

116

Chemstat 273-E PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Chemstat 273-E

CAS #

-

Common name

Ethoxylated stearyl amine

Common synonym

2,2'-(Octadecylimino)bisethanol

Empirical formula

-

Formula

10213-78-2

C22H47NO2

CH3(CH2)17N(CH2CH2OH)2

EC number

-

233-520-3

Molecular mass

daltons

357.61

Chemical category

-

amine

-

solid

PHYSICAL PROPERTIES State Color

off white

Color, Gardner scale

-

Boiling point

o

C

4 max 217

Melting point

o

C

49.4

Specific gravity at 25 C

-

0.96

Vapor density

-

1

Volume resistivity

Ohm-cm

1.0E+13 (0.8% in PP)

Ohm

0.8 (0.8% in PP)

Solubility in water at 25 C

g/l

insoluble

Volatility

wt%

1

Health

2

o

Surface resistance o

HEALTH & SAFETY NFPA classification

Flammability

1

Reactivity

0

HMIS personal protection

Safety glasses with side shields, NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge, body covering-clothing, neoprene or butyl rubber gloves.

UN risk phrases, R

-

36/37/38

US safety phrases, S

-

26

DOT class

-

not regulated

ICAO/IATA class

-

not regulated

TDG class

-

not regulated

Antistatics Databook / Copyrights 2014; ChemTec Publishing

117

Chemstat 273-E PARAMETER

UNIT

VALUE

Proper shipping name

not regulated

Autoignition temperature

o

C

>232

Flash point

o

C

>199

Flash point method

-

Eye irritation (human)

Causes eye burns. Contact with product at elevated temperatures can result in thermal burns

Ingestion

May cause severe irritation to digestive tract including nausea, vomiting, diarrhea

First aid, eyes

Immediately flush eyes with water for at least 15 minutes. Do not let victim rub eyes. Seek medical attention immediately

First aid, skin

Immediately wash skin with plenty of soap and water while removing contaminated clothing and shoes. Get medical attention. Contaminated clothing should be discarded in a manner which limits further exposure

First aid, inhalation

Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

COC

ECOLOGICAL PROPERTIES Partition coefficient, log Kow

-

6.85

-

PCC Chemax

USE & PERFORMANCE Manufacturer

Antistatics Databook / Copyrights 2014; ChemTec Publishing

118

Chemstat AC-2000 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Chemstat AC-2000

CAS #

-

Common name

Dodecanamide, N, N- bis (2-hydroxyethyl)

Empirical formula

-

Formula

120-40-1

C16H33NO3

O (HOCH2CH2)2NCO(CH2)10CH3

Mixture

-

yes

EC number

-

204-393-1

Molecular mass

daltons

287.44

Chemical category

-

masterbatch

-

solid

PHYSICAL PROPERTIES State Odor

none

Color

off white C

160

Melting point

o

Volume resistivity

Ohm-cm

1.0E+10 (5-10% in PP)

Surface resistance

Ohm

0.13-0.05 (5-10% in PP)

Solubility in water at 25oC

g/l

insoluble

Volatility

wt%

1

Health

2

Flammability

1

Reactivity

0

HEALTH & SAFETY NFPA classification

HMIS personal protection

Safety glasses with side shields, NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge, body covering-clothing, neoprene or butyl rubber gloves

Food approval(s)

Meets 21CFR 178.3130 requirements for polyolefins at use levels up to 2.5%

UN risk phrases, R

-

36/37/38

US safety phrases, S

-

26

DOT class

-

not regulated

ICAO/IATA class

-

not regulated

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119

Chemstat AC-2000 PARAMETER

UNIT

VALUE not regulated

TDG class

-

Proper shipping name

not regulated

Skin irritation

Contact causes skin irritation

Eye irritation (human)

Contact causes eye irritation

Ingestion

May cause irritation to digestive tract including nausea, vomiting, or diarrhea

Chronic effects

Immediately flush eyes with water for at least 15 minutes. Do not let victim rub eyes. Seek medical attention immediately

First aid, eyes

Immediately wash skin with plenty of soap and water while removing contaminated clothing and shoes. Get medical attention. Contaminated clothing should be discarded in a manner which limits further exposure. If molten material contacts skin, cool rapidly with cold water. Do not attempt to peel from skin

First aid, skin

Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP, or OSHA

ECOLOGICAL PROPERTIES Partition coefficient, log Kow

-

2.89

-

PCC Chemax

USE & PERFORMANCE Manufacturer Carrier resin

-

PP

Concentration of active ingredients

wt%

20

Outstanding properties

Non-amine and military applications

Recommended for polymers

PP

Recommended dosage

wt%

Processing methods

Extrusion, injection molding

Additive application method

Internal

Antistatics Databook / Copyrights 2014; ChemTec Publishing

5 to 10

120

Chemstat LD-100 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Chemstat LD-100

CAS #

-

Common name

Dodecanamide, N, N- bis (2-hydroxyethyl)

Common synonym

Lauric diethanolamide

Formula

120-40-1

O (HOCH2CH2)2NCO(CH2)10CH3

Mixture

-

yes

EC number

-

204-393-1

Chemical category

-

amine

Moisture content

wt%

0.5

-

solid

PHYSICAL PROPERTIES State Odor

mild fatty

Color

off white

Boiling point

o

C

148

Specific gravity at 25 C

-

0.98

Vapor density

-

1

Volume resistivity

Ohm-cm

1.0E+10 (LDPE 0.5%, HDPE 0.8%, PP 1%)

Surface resistance

Ohm

0.05 (LDPE 0.5%, HDPE 0.8%, PP 2%)

mg KOH/g

3 max

g/l

dispersible

Health

2

o

Acid number Solubility in water at 25 C o

HEALTH & SAFETY NFPA classification

Flammability

1

Reactivity

0

HMIS personal protection

Safety glasses with side shields, NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge, body covering-clothing, neoprene or butyl rubber gloves

Food approval(s)

21 CFR 178.3130

UN risk phrases, R

-

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36/37/38 121

Chemstat LD-100 PARAMETER

UNIT

VALUE

US safety phrases, S

-

22,26

DOT class

-

not regulated

ICAO/IATA class

-

not regulated

TDG class

-

not regulated

Proper shipping name

not regulated

Flash point

o

Flash point method

-

Skin irritation

Contact causes skin irritation. Contact with product at elevated temperatures can result in thermal burns. irritation. DEA may be absorbed by the skin producing mildly toxic effects

Eye irritation (human)

Contact causes eye irritation. Contact with product at elevated temperatures can result in thermal burns

Ingestion

May cause irritation to digestive tract including nausea, vomiting, or diarrhea. DEA is moderately toxic by ingestion

Chronic effects

Immediately flush eyes with water for at least 15 minutes. Do not let victim rub eyes. Seek medical attention immediately

First aid, eyes

Immediately wash skin with plenty of soap and water while removing contaminated clothing and shoes. Get medical attention. Contaminated clothing should be discarded in a manner which limits further exposure. If molten material contacts skin, cool rapidly with cold water. Do not attempt to peel from skin

First aid, skin

Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention

First aid, inhalation

Not listed as carcinogenic according to IARC, NTP, or OSHA

C

93 PMCC

ECOLOGICAL PROPERTIES Partition coefficient, log Kow

-

2.89

Manufacturer

-

PCC Chemax

Concentration of active ingredients

wt%

99

USE & PERFORMANCE

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122

Chemstat LD-100 PARAMETER

UNIT

VALUE

Outstanding properties

Works well at low relative humidity, meets military specification, FDA approved

Recommended for polymers

PE, PP

Recommended dosage

LDPE, HDPE (0.5 to 0.8%), PP (1 to 2%)

Additive application method

Internal

Antistatics Databook / Copyrights 2014; ChemTec Publishing

123

Cyastat SN PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Cyastat SN

CAS #

-

Common name

Stearamidopropyldimethyl-beta-hydroxyethylammonium nitrate

Common synonym

Quaternary ammonium compound

Empirical formula

-

2764-13-8

C25H53O5N3

Formula

O O N O CH3(CH2)16CN(CH2)3NCH2CH2OH

Mixture

-

yes

Molecular mass

daltons

475

Chemical category

-

amine

State

-

liquid

Odor

-

isopropyl alcohol

Color

-

yellow to amber

Color, Gardner scale

-

5 max

Boiling point

o

PHYSICAL PROPERTIES

C

83

Specific gravity at 25 C

-

0.95

Vapor density

-

50

pH

-

4 to 6

Health

2

Flammability

3

Reactivity

0

o

HEALTH & SAFETY NFPA classification

HMIS personal protection

Safety glasses with side shields, NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge, body covering-clothing, neoprene or butyl rubber gloves

UN/NA class

-

1993

DOT class

-

group II, class 3

ICAO/IATA class

-

group II, class 3

TDG class

-

group II, class 3

Proper shipping name

Flammable liquid, n.o.s.

Flash point

o

C

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12 124

Cyastat SN PARAMETER

UNIT

VALUE

Animal testing, acute toxicity, Rat oral LD50

mg/kg

2500

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

3300

First aid, eyes

Rinse immediately with plenty of water for at least 15 minutes. Obtain medical attention immediately

First aid, skin

Remove contaminated clothing and shoes without delay. Wash immediately with plenty of water. Do not reuse contaminated clothing without laundering. Get medical attention if pain or irritation persists after washing or if signs and symptoms of overexposure appear

First aid, inhalation

Remove to fresh air. If breathing is difficult, give oxygen. Obtain medical advice if there are persistent symptoms

ECOLOGICAL PROPERTIES Partition coefficient, log Kow

-

3.41

USE & PERFORMANCE Manufacturer

Cytec Industries Inc.

Concentration of active ingredients

wt%

Antistatics Databook / Copyrights 2014; ChemTec Publishing

48.5 to 51.5

125

Cyastat SP PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Cyastat SP

CAS #

-

Common name

Stearamidopropyldimethyl-hydroxyethylammonium-dihydrogen phosphate

Common synonym

Quaternary ammonium compound

Empirical formula

-

3758-54-1

C25H53O6N2P

Formula

O O P OH O OH CH3(CH2)16CN(CH2)3NCH2CH2OH

Mixture

-

yes

EC number

-

223-165-2

Molecular mass

daltons

510

Chemical category

-

amine

-

liquid

Color

-

light yellow

Color, Gardner scale

-

5 max

Boiling point

o

PHYSICAL PROPERTIES State

C

80

Specific gravity at 25 C

-

0.94

Vapor density

-

65

o

pH

-

6 to 8

Solubility in water at 25oC

g/l

appreciable

Tensile strength

MPa

25.1

Tensile elongation

%

1077

Health

2

HEALTH & SAFETY NFPA classification

Flammability

3

Reactivity

0

UN/NA class

-

1993

DOT class

-

group II, class 3

ICAO/IATA class

-

group II, class 3

TDG class

-

group II, class 3

Proper shipping name

Flammable liquid, n.o.s.

Flash point

o

C

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14 126

Cyastat SP PARAMETER

UNIT

VALUE

Animal testing, acute toxicity, Rat oral LD50

mg/kg

3300

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

5000

First aid, eyes

Rinse immediately with plenty of water for at least 15 minutes. Obtain medical attention immediately

First aid, skin

Wash immediately with plenty of water and soap.

First aid, inhalation

Remove to fresh air. If breathing is difficult, give oxygen. Obtain medical advice if there are persistent symptoms

ECOLOGICAL PROPERTIES Partition coefficient, log Kow

-

2.42

USE & PERFORMANCE Manufacturer

Cytec Industries Inc.

Concentration of active ingredients

wt%

Antistatics Databook / Copyrights 2014; ChemTec Publishing

33.5 to 36.5

127

Deuteron LE 512 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Deuteron LE 512

Common name

Tetraalkyl ammonium methylsulfate

Common synonym

Quaternary ammonium compound

Mixture

-

no

EC number

-

221-108-6

Chemical category

-

amine

State

-

solid

Color

-

yellowish

Melting point

o

PHYSICAL PROPERTIES

Specific gravity at 25 C o

C

-

80 0.96

pH

-

7.5

Solubility in water at 25oC

g/l

unlimited

Tensile strength

MPa

45

Tensile elongation

%

15

Flexural modulus

MPa

2900

Mold shrinkage

%

1.7 to 2.0

HEALTH & SAFETY HMIS personal protection

Protective gloves nitrile rubber EN 374, safety glasses/face shield, protective clothing

UN risk phrases, R

-

22,50/53

US safety phrases, S

-

29

UN/NA class

-

3082

DOT class

-

group III, class 9

ICAO/IATA class

-

group III, class 9

TDG class

-

group III, class 9

Autoignition temperature

o

C

Flash point

o

C

Animal testing, acute toxicity, Rat oral LD50

mg/kg

First aid, eyes

In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice

First aid, skin

In case of contact with skin wash off immediately with soap and water

First aid, inhalation

Ensure supply of fresh air. In the event of symptoms take medical treatment

Antistatics Databook / Copyrights 2014; ChemTec Publishing

300 104 530

128

Deuteron LE 512 PARAMETER

UNIT

VALUE

mg/l

0.1 max

Manufacturer

-

Deuteron GmbH

Concentration of active ingredients

wt%

100

Recommended for polymers

PU systems

ECOLOGICAL PROPERTIES Aquatic toxicity, Daphnia magna, 48-h LC50

USE & PERFORMANCE

Recommended dosage

wt%

Additive application method

Internal

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1 to 2.5

129

Deuteron LE 80 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Deuteron LE 80

Common name

Lauryltrialkylammonium methylsulfate 80%, n-butanol 20%

Common synonym

Quaternary ammonium compound

Mixture

-

yes

Chemical category

-

amine

State

-

liquid

Melting point

o

Specific gravity at 25oC

-

0.94

Vapor density

-

20

PHYSICAL PROPERTIES C

0

pH

-

8

Viscosity at 20oC

mPas

150

Solubility in water at 25oC

g/l

miscible

Tensile strength

MPa

44

Tensile elongation

%

40

Flexural modulus

MPa

2700

Mold shrinkage

%

0.6 to 0.8

HEALTH & SAFETY HMIS personal protection

Protective gloves nitrile rubber EN 374, safety glasses/face shield, protective clothing

UN risk phrases, R

-

10,22,41,50/53,67

US safety phrases, S

-

16,29

UN/NA class

-

1120

DOT class

-

group III, class 3

ICAO/IATA class

-

group III, class 3

TDG class

-

group III, class 3

Autoignition temperature

o

C

370

Flash point

o

C

35

Explosive LEL

wt%

1.4

Explosive UEL

wt%

11.3

Animal testing, acute toxicity, Rat oral LD50

mg/kg

530

First aid, eyes

In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice

First aid, skin

In case of contact with skin wash off immediately with soap and water

Antistatics Databook / Copyrights 2014; ChemTec Publishing

130

Deuteron LE 80 PARAMETER

UNIT

VALUE

First aid, inhalation

Ensure supply of fresh air. In the event of symptoms take medical treatment

ECOLOGICAL PROPERTIES Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.1 max

Manufacturer

-

Deuteron GmbH 85

USE & PERFORMANCE Concentration of active ingredients

wt%

Recommended for polymers

PUR polyether or polyester based

Recommended dosage

wt%

Additive application method

Internal

Antistatics Databook / Copyrights 2014; ChemTec Publishing

2.5

131

Duoquad T-50 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Duoquad T-50

CAS #

-

Common name

Pentamethyltallowalkyl-1,3-propane

Mixture

-

yes

EC number

-

271-762-1

Chemical category

-

amine

Moisture content

wt%

16 to 24

68607-29-4

PHYSICAL PROPERTIES State

-

liquid

Odor

-

alcohol-like

Color

-

yellow

Color, Gardner scale

-

7 max

Boiling point

o

C

80

Melting point

o

C

-18

Pour point

o

C

Density at 20oC

kg/m3

-15 930

pH

-

6 to 9

Solubility in water at 25oC

g/l

soluble

Solubility in solvents

methanol, acetone

HEALTH & SAFETY NFPA classification

HMIS classification

Health

3

Flammability

3

Reactivity

0

Health

3

Flammability

3

Reactivity

0

HMIS personal protection

Splash goggles, full suit, vapor respirator, gloves, and boots

UN/NA class

-

2924

DOT class

-

group II, class 3

ICAO/IATA class

-

group II, class 3

TDG class

-

group II, class 3

Proper shipping name

Flammable liquids, corrosive, n.o.s. (isopropyl alcohol, quaternary ammonium salts)

Autoignition temperature

o

C

400

Flash point

o

C

12

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132

Duoquad T-50 PARAMETER

UNIT

VALUE

Flash point method

-

PMCC

Explosive LEL

wt%

2

Explosive UEL

wt%

12.7

Animal testing, acute toxicity, Rat oral LD50

mg/kg

945

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

12800

Skin irritation

Corrosive to the skin. Practically nontoxic in contact with skin

Eye irritation (human)

Corrosive to the eyes

Carcinogenicity

IARC, NTP, OSHA, ACGIH: Not listed

ECOLOGICAL PROPERTIES Biodegradation probability

Inherently biodegradable

USE & PERFORMANCE Manufacturer

-

AKZO Nobel

Concentration of active ingredients

wt%

48-52

Antistatics Databook / Copyrights 2014; ChemTec Publishing

133

Ethofat 242-25 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ethofat 242-25

CAS #

-

Common name

Tall oil, ethoxylated

Common synonym

Polyoxyethylene (15) tall oil acid

Mixture

-

yes

Chemical category

-

amine

Moisture content

wt%

1.5 to 3

65071-95-6

PHYSICAL PROPERTIES State

-

liquid

Odor

-

bland

Color

-

amber

Color, Gardner scale

-

12 max

Boiling point

o

C

300

Melting point

o

C

10

Pour point

o

C

Specific gravity at 20oC

-

15 1.081

Vapor pressure at 20oC

kPa

0.01 max

Acid number

mg KOH/g

1 Max

Saponification value

mg KOH/g

55 to 65

pH

-

5 to 7

Surface tension at 25oC

mN/m

42

Solubility in water at 25 C

g/l

soluble

Health

0

Flammability

1

o

HEALTH & SAFETY NFPA classification

HMIS classification

Reactivity

0

Health

0

Flammability

1

Reactivity

0

HMIS personal protection

Safety glasses and clothing

DOT class

-

not regulated

ICAO/IATA class

-

not regulated

TDG class

-

not regulated

Proper shipping name

not regulated

Flash point

o

Flash point method

-

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

274 PMCC 134

Ethofat 242-25 PARAMETER

UNIT

VALUE

Animal testing, acute toxicity, Rat oral LD50

mg/kg

5000 min

Ingestion

Not a probable route of exposure

Chronic effects

None known for this compound

First aid, eyes

Flush with water. Consult physician if symptoms persist

First aid, skin

Wash with soap and water. For thermal burns, immediately flush with cold water. Do not attempt to remove polymer from skin. Obtain medical attention

First aid, inhalation

Leave exposed area and seek fresh air. If irritation persists seek medical attention

USE & PERFORMANCE Manufacturer

-

AKZO Nobel

Concentration of active ingredients

wt%

98-100

Antistatics Databook / Copyrights 2014; ChemTec Publishing

135

Ethomeen 18-25 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ethomeen 18-25

CAS #

-

Common name

Poly(oxy-1,2-ethanediyl), a,a'[(octadeylimino)

Common synonym

Stearylamine ethoxylate

Formula

26635-92-7

CH3(CH2)17N(CH2CH2 OCH2CH2 nOH)2

Chemical category

-

amine

Moisture content

wt%

1

State

-

solid

Odor

-

amine-like

Color

-

amber

Color, Gardner scale

-

8 max

Boiling point

o

C

300

Melting point

o

C

9

Pour point

o

C

PHYSICAL PROPERTIES

Density at 20 C

kg/m

o

10 3

1015

Vapor pressure at 20 C

kPa

0.01 max

pH

-

11 to 11.6

Viscosity at 25 C

mPas

150

Solubility in water at 25oC

g/l

soluble

Health

2

o

o

HEALTH & SAFETY NFPA classification

HMIS classification

Flammability

1

Reactivity

0

Health

2

Flammability

1

Reactivity

0

HMIS personal protection

Splash goggles, synthetic apron, and vapor respirator

DOT class

-

not regulated

ICAO/IATA class

-

not regulated

TDG class

-

not regulated

Autoignition temperature

o

C

150

Flash point

o

C

200

Antistatics Databook / Copyrights 2014; ChemTec Publishing

136

Ethomeen 18-25 PARAMETER

UNIT

VALUE

Animal testing, acute toxicity, Rat oral LD50

mg/kg

1200 to 1500

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

689

Skin irritation

Severely irritating to the skin. Practically non-toxic in contact with skin

Eye irritation (human)

Severely irritating to the eyes

First aid, eyes

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately

First aid, skin

Wash with soap and water. Get medical attention if irritation develops. Cold water may be used

First aid, inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear

Carcinogenicity

IARC, NTP, OSHA, ACGIH: Not listed

ECOLOGICAL PROPERTIES Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

10000 max

USE & PERFORMANCE Manufacturer

-

AKZO Nobel

Davis scale

-

14.4

Concentration of active ingredients

wt%

98-100

Antistatics Databook / Copyrights 2014; ChemTec Publishing

137

Ethomeen C-12 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ethomeen C-12

CAS #

-

Common name

Ethanol, 2,2'-iminobis-, n-coco alkyl derivs.

EC number

-

263-163-9

Chemical category

-

amine

Moisture content

wt%

1

61791-31-9

PHYSICAL PROPERTIES State

-

liquid

Odor

-

amine-like

Color

colorless to light yellow

Color, Gardner scale

-

Boiling point

o

C

268

Melting point

o

C

6

Pour point

o

C

8

Density at 20oC

kg/m3

899

-

10

Vapor density

4 max

Vapor pressure at 20 C

kPa

0.01 max

Viscosity at 25oC

mPas

130

Solubility in water at 25oC

wt%

soluble

Health

3

Flammability

1

o

HEALTH & SAFETY NFPA classification

HMIS classification

Reactivity

0

Health

3

Flammability

1

Reactivity

0

HMIS personal protection

Face shield, full suit, vapor respirator, and gloves.

DOT class

-

group III, class 8

ICAO/IATA class

-

group III, class 8

TDG class

-

group III, class 8

Proper shipping name

Amines, liquid, corrosive, n.o.s. (alkoxylated fatty amines)

Autoignition temperature

o

C

150

Flash point

o

C

100 min

Flash point method

-

Antistatics Databook / Copyrights 2014; ChemTec Publishing

PMCC 138

Ethomeen C-12 PARAMETER

UNIT

VALUE

Animal testing, acute toxicity, Rat oral LD50

mg/kg

6600

Skin irritation

Corrosive to the skin. May cause sensitization by skin contact. Practically non-toxic in contact with skin

Eye irritation (human)

Severely irritating to the eyes

First aid, eyes

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately

First aid, skin

Wash with soap and water. Get medical attention if irritation develops. Cold water may be used

First aid, inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear

Carcinogenicity

IARC, NTP, OSHA, ACGIH: Not listed

ECOLOGICAL PROPERTIES Biodegradation probability

Readily biodegradable

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.032

USE & PERFORMANCE Manufacturer

-

AKZO Nobel

Davis scale

-

12.2

Concentration of active ingredients

wt%

97-100

Antistatics Databook / Copyrights 2014; ChemTec Publishing

139

Ethomeen C-15 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ethomeen C-15

CAS #

-

Common name

Amines, coco alkyl, ethoxylated

Common synonym

Polyoxyethylene (5) cocoalkylamines

Chemical category

-

amine

Moisture content

wt%

1

-

liquid

Odor

-

amine-like

Color

colorless to light yellow

Color, Gardner scale

-

Boiling point

o

C

300

Melting point

o

C

-9

Pour point

o

C

61791-14-8

PHYSICAL PROPERTIES State

7 max

-7

Density at 20 C

kg/m

Vapor density

-

10

Vapor pressure at 20oC

kPa

0.01 max

pH

-

9 to 11

mPas

150

o

Viscosity at 25 C o

3

Solubility in water at 25 C

976

soluble

o

HEALTH & SAFETY NFPA classification

HMIS classification

Health

3

Flammability

1

Reactivity

0

Health

3

Flammability

1

Reactivity

0

HMIS personal protection

Face shield, full suit, vapor respirator, and gloves.

UN risk phrases, R

-

22,41,51/53

US safety phrases, S

-

26,39,61

DOT class

-

not regulated

ICAO/IATA class

-

not regulated

TDG class

-

not regulated

Proper shipping name

not regulated

Autoignition temperature

o

C

Antistatics Databook / Copyrights 2014; ChemTec Publishing

>150 140

Ethomeen C-15 PARAMETER

UNIT

Flash point

o

Flash point method

-

CC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

750

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

2000

Skin irritation

Corrosive to the skin. May cause sensitization by skin contact. Practically non-toxic in contact with skin

Eye irritation (human)

Severely irritating to the eyes

First aid, eyes

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately

First aid, skin

Wash with soap and water. Get medical attention if irritation develops. Cold water may be used

First aid, inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear

Carcinogenicity

IARC, NTP, OSHA, ACGIH: Not listed

C

VALUE >240

ECOLOGICAL PROPERTIES Biodegradation probability

Inherently biodegradable

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

1.41

Manufacturer

-

AKZO Nobel

Davis scale

-

13.3

Concentration of active ingredients

wt%

98-100

USE & PERFORMANCE

Antistatics Databook / Copyrights 2014; ChemTec Publishing

141

Ethomeen S-15 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ethomeen S-15

CAS #

-

Common name

Amines, soya alkyl, ethoxylated

Common synonym

Polyoxyethylene (5) soyaalkylamines

Chemical category

-

amine

Moisture content

wt%

1

-

liquid

61791-24-0

PHYSICAL PROPERTIES State Odor

-

amine-like

Color

-

amber

Color, Gardner scale

-

10 max

Boiling point

o

C

>300

Melting point

o

C

6

Pour point

o

C

Density at 20 C

kg/m

Vapor pressure at 20oC

kPa

o

7 3

952 0.01 max

pH

-

9 to 11

Viscosity at 25oC

mPas

150

Surface tension at 25oC

mN/m

33

Health

3

Flammability

1

HEALTH & SAFETY NFPA classification

HMIS classification

Reactivity

0

Health

3

Flammability

1

Reactivity

0

HMIS personal protection

Face shield, full suit, vapor respirator, and gloves.

UN/NA class

-

2735

DOT class

-

group III, class 8

ICAO/IATA class

-

group III, class 8

TDG class

-

group III, class 8

Proper shipping name

Amines, liquid, corrosive, n.o.s. (alkoxylated fatty amines)

Autoignition temperature

o

C

150

Flash point

o

C

150 min

Flash point method

-

Antistatics Databook / Copyrights 2014; ChemTec Publishing

PMCC 142

Ethomeen S-15 PARAMETER

UNIT

VALUE

Animal testing, acute toxicity, Rat oral LD50

mg/kg

1260

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

20000 min

Skin irritation

Corrosive to the skin. May cause sensitization by skin contact. Practically non-toxic in contact with skin

Eye irritation (human)

Severely irritating to the eyes

First aid, eyes

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately

First aid, skin

Wash with soap and water. Get medical attention if irritation develops. Cold water may be used

First aid, inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear

Carcinogenicity

IARC, NTP, OSHA, ACGIH: Not listed

Mutagenicity

None

ECOLOGICAL PROPERTIES Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

10000 max

-

AKZO Nobel

USE & PERFORMANCE Manufacturer Davis scale

-

11.1

Concentration of active ingredients

wt%

98-100

Antistatics Databook / Copyrights 2014; ChemTec Publishing

143

Ethomeen T-12 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ethomeen T-12

CAS #

-

Common name

Ethanol, 2,2'-iminobis, n-tallow alkyl derivs.

Common synonym

Bis(2-hydroxyethyl)tallowalkylamines

61791-44-4

EC number

-

263-177-5

Chemical category

-

amine

Moisture content

wt%

1

State

-

liquid

Odor

-

amine-like

Color

-

amber

Color, Gardner scale

-

6 max

Boiling point

o

C

>300

Melting point

o

C

29

Pour point

o

C

PHYSICAL PROPERTIES

Density at 25 C

kg/m

o

Vapor pressure at 20 C o

33 3

kPa

Solubility in water at 25oC Solubility in solvents

916 0.01 max very slight

alcohol

HEALTH & SAFETY NFPA classification

HMIS classification

Health

3

Flammability

1

Reactivity

0

Health

3

Flammability

1

Reactivity

0

HMIS personal protection

Face shield, full suit, vapor respirator, and gloves.

UN/NA class

-

2735

DOT class

-

group III, class 8

ICAO/IATA class

-

group III, class 8

TDG class

-

group III, class 8

Proper shipping name

Amines, liquid, corrosive, n.o.s. (alkoxylated fatty amines)

Autoignition temperature

o

C

150

Flash point

o

C

100 min

Antistatics Databook / Copyrights 2014; ChemTec Publishing

144

Ethomeen T-12 PARAMETER

UNIT

VALUE

Flash point method

-

PMCC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

1200 to 1500

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

20000 min

Skin irritation

Corrosive to the skin. May cause sensitization by skin contact. Practically non-toxic in contact with skin

Eye irritation (human)

Severely irritating to the eyes

First aid, eyes

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately

First aid, skin

Wash with soap and water. Get medical attention if irritation develops. Cold water may be used

First aid, inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear

Carcinogenicity

IARC, NTP, OSHA, ACGIH: Not listed

Mutagenicity

None

ECOLOGICAL PROPERTIES Aquatic toxicity, Bluegill sunfish, 96-h LC50

mg/l

0.11

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

10000 max

Manufacturer

-

AKZO Nobel

Davis scale

-

10.1

Concentration of active ingredients

wt%

97-100

USE & PERFORMANCE

Antistatics Databook / Copyrights 2014; ChemTec Publishing

145

Ethomeen T-15 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ethomeen T-15

CAS #

-

Common name

Amines, tallow alkyl, ethoxylated

Common synonym

Polyoxyethylene (5) tallowalkylamines

Chemical category

-

amine

Moisture content

wt%

1

-

liquid

61791-26-2

PHYSICAL PROPERTIES State Odor

-

amine-like

Color

-

amber

Color, Gardner scale

-

7 max

Boiling point

o

C

>300

Melting point

o

C

12

Pour point

o

C

13

Density at 25 C

kg/m

Vapor density

-

10

Vapor pressure at 20oC

kPa

0.01 max

pH

-

11 to 11.6

mN/m

34

o

Surface tension at 25 C o

3

Solubility in water at 25 C

very slight

o

Solubility in solvents

950

acetone, isopropanol, Stoddard solvent

HEALTH & SAFETY NFPA classification

HMIS classification

Health

2

Flammability

1

Reactivity

0

Health

2

Flammability

1

Reactivity

0

HMIS personal protection

Face shield, full suit, vapor respirator, and gloves.

DOT class

-

not regulated

ICAO/IATA class

-

not regulated

TDG class

-

not regulated

Proper shipping name

not regulated

Autoignition temperature

o

C

150

Flash point

o

C

100 min

Antistatics Databook / Copyrights 2014; ChemTec Publishing

146

Ethomeen T-15 PARAMETER

UNIT

VALUE

Flash point method

-

PMCC

Animal testing, acute toxicity, Rat oral LD50

mg/kg

1200 to 1500

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg

20000 min

Skin irritation

Corrosive to the skin. May cause sensitization by skin contact. Practically non-toxic in contact with skin

Eye irritation (human)

Severely irritating to the eyes

First aid, eyes

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately

First aid, skin

Wash with soap and water. Get medical attention if irritation develops. Cold water may be used

First aid, inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear

Carcinogenicity

IARC, NTP, OSHA, ACGIH: Not listed

Mutagenicity

None

ECOLOGICAL PROPERTIES Biodegradation probability

Readily biodegradable

Aquatic toxicity, Bluegill sunfish, 96-h LC50

mg/l

0.11

Aquatic toxicity, Daphnia magna, 48-h LC50

mg/l

0.011

-

AKZO Nobel

USE & PERFORMANCE Manufacturer Davis scale

-

11.2

Concentration of active ingredients

wt%

98-100

Antistatics Databook / Copyrights 2014; ChemTec Publishing

147

Ethoquad C/12 PARAMETER

UNIT

VALUE

GENERAL INFORMATION Name

Ethoquad C/12

CAS #

-

Common name

Cocobis(2-hydroxyethyl)methylammonium chloride

Common synonym

Quaternary ammonium compound

70750-47-9

Mixture

-

yes

EC number

-

274-846-6

Molecular mass

daltons

324.5

Chemical category

-

amine

Moisture content

wt%

3

PHYSICAL PROPERTIES State

-

liquid

Odor

-

negligible

Color

-

dark yellow 9 max

Color, Gardner scale

-

Boiling point

o

C

Melting point

o

C

Density at 20 C

kg/m

Vapor density

-

o

80 -13 3

970 2.07 (IPA)

pH

-

6 to 9

Viscosity at 25oC

mPas

250

mN/m

34 to 38

Surface tension at 25oC Solubility in water at 25 C

soluble

o

HEALTH & SAFETY NFPA classification

HMIS classification

Health

3

Flammability

3

Reactivity

0

Health

3

Flammability

3

Reactivity

0

HMIS personal protection

Suitable respiratory protection, neoprene or nitrile gloves, safety goggles, protective clothing

UN risk phrases, R

-

11,22,34,50,67

US safety phrases, S

16,26,28,36/39,45,57

UN/NA class

-

2924

DOT class

-

group III, class 3

Antistatics Databook / Copyrights 2014; ChemTec Publishing

148

Ethoquad C/12 PARAMETER

UNIT

VALUE

ICAO/IATA class

-

group III, class 3

TDG class

-

group III, class 3

Proper shipping name

Flammable liquid, corrosive, n.o.s. (Cocobis(2-hydroxyethyl)methylammonium chloride/2-Propanol mixture)

Flash point

o

C

15

ACGIH, TLV – TWA 8h

3

mg/m

983

NIOSH, TLV – TWA 8h

mg/m3

980

OSHA, TLV – TWA 8h

mg/m

980

ACGIH, TLV – TWA 8h

ppm

400

NIOSH, TLV – TWA 8h

ppm

400

3

OSHA, TLV – TWA 8h

ppm

400

Animal testing, acute toxicity, Rat oral LD50

mg/kg

200 to 2000

Animal testing, acute toxicity, Rabbit dermal LD50

mg/kg